Abstract
This is a research on hazardous characteristics and potentials of bottom ash from 9 municipal solid waste combustors(200 tons/day) of Korea by the test methods of leaching and content. The leaching method was performed by Waste Test Method of Korea. In case of the content method, mercury was determined by thermal decomposition amalgamation atomic absorption spectrometer, other 9 elemets including Pb, which were pretreated by U.S.EPA SW-846 3050B method, were determined by flame atomic absorption spectrometer(FAAS) or inductively coupled plasma atomic emission spectrometer(ICP-AES). Results of leaching test showed that Pb and Cu was main pollutants. It was interested that the distribution rate of metals' contents of each combustors was similar and the rank of concentration was Fe>Zn>Cu>Mn>Pb>Cr>As>Cd>Hg.
본 연구에서는 우리나라 생활폐기물 대형소각시설(200톤/일 이상) 9개소에서 발생되는 소각재중, 바닥재에 대한 금속류의 용출시험 및 함량시험을 수행하여 유해특성과 유해잠재성을 고찰하였다. 용출시험은 우리나라 폐기물공정시험방법에 따라 수행하였으며, 함량시험은 수은(Hg)의 경우 열분해금아말감원자흡광분광기(TDA-AAS)로 측정하고, 납 등 9개 원소는 US-EPASW-846 3050B방법으로 전처리하고 불꽃원자흡광분광기(FAAS) 또는 유도결합플라스마원자발광분광기(ICP-AES)로 측정하였다. 용출시험 결과, 납과 구리가 주 오염물질이었다. 함량시험결과, 철이 가장 높은 농도로 나타났고 농도는 Fe>Zn>Cu>Mn>Pb>Cr>As>Cd>Hg 순으로 나타났으며, 각 소각시설마다 농도순이 평균적으로는 같았다.