Structural and Microwave Dielectric Properties of the Mg$_{1-x}Sr_xTiO-3$ Ceramics with Sintering Temperature and Sr Mole Ratio

소결온도와 Sr몰비에 따른 Mg$_{1-x}Sr_xTiO-3$ 세라믹스의 구조 및 마이크로파 유전특성

  • Published : 2001.05.01

Abstract

The $Mg_{1-x}Sr_xTiO_3\;(x=0.02{\sim}0.08)$ ceramics were fabricated by the conventional mixed oxide method. The sintering temperature and time were $1250^{\circ}C{\sim}1350^{\circ}C$, 2hr., respectively. From the X-ray diffraction patterns, it was found that the perovskite $SrTiO_3$ and ilmenite $MgTiO_3$ structures were coexisted in the $Mg_{1-x}Sr_xTiO_3\;(x=0.02{\sim}0.08)$ ceramics. The dielectric constant( ${\epsilon}_r$) was increased with addition of $SrTiO_3$. The temperature coefficient of resonant frequency( ${\tau}_f$) was gradually varied from negative value to the positive value with increasing the $SrTiO_3$. The temperature coefficient of resonant frequency of the $Mg_{1-x}Sr_xTiO_3(x=0.036)$ ceramics was near zero, where the dielectric constant, quality factor, and ${\tau}_f$ were 20.65, 95120 and +1.3ppm/$^{\circ}C$, respectively.

Keywords

References

  1. N. Negas, G. Yeager, S. Bell, and R. Amren, 'Chemistry and Properties of Temperature Compensated Microwave Dielectrics', NIST spec. publ. 804. in Chemistry of Electronic Ceramic Materials, pp. 21, 1991
  2. E. Nagata, J. Tanaka, M. Tsutumi and E. Bannai, 'Distribution of Calcium Ion in the Crystal of $MgTiO_3-CaTiO_3$ System', Bull. Chem. Soc. Jpn., 56, pp. 3173-3174, 1983 https://doi.org/10.1246/bcsj.56.3173
  3. D. Kolar and D. Suvorov, 'High Permittivity Microwave Ceramics', Eur. J. Solid State Inorg. Chem., 32, pp. 751-760. 1995
  4. 이경희 역, '세라믹 유전체 공학', 대광출판사, pp.341-346, 1991
  5. K. Wakino et al., 'Dielectric Materials for Dielectric Resonator', in 1976 Joint Convention Record of Four Institute of Electrical Engineers, No. 235, Japan, 1976
  6. J. Burn, 'Flux Sintered $BaTiO_3$ Dielectrics', J. Mater, Sci., 117, pp.1398-1408, 1982 https://doi.org/10.1007/BF00752252
  7. K. Wakino et al., 'Microwave Characteristics of $(Zn,Sn)TiO_4\;and\;BaO-PhO-Nd_2O_3-TiO_2$ Dielectric Resonator', J. Am. Ceram. Soc., 64(7), 278, 1984
  8. V. M. Ferreira et al., 'The Effect of Cr and La on $MgTiO_3\;and\;MgTiO_3-CaTiO_3$ Microwave Dielectric Ceramics', J. Mater. Res., Vol.12, No.12, pp.3293-3299, 1997
  9. M. Furuya et al., 'Microwave Dielectric Properties for $Ba(Mg_{1/3}Ta_{2/3})O_{3}\;-A(Mg_{1/2}W_{1/2})O_{3}$ (A=Ba, Sr and Ca) Ceramics', Jpn. J. Appl. Phys., Vol.33, No.9B, 1994
  10. 이영희 등, '소결온도에 따른 0.9MgTiO3-0.1SrTiO3 세라믹스의 구조 및 마이크로파 유전특성', 대한전기학회지, Vol.49C, No.5, pp.294-298, 2000
  11. B. W. Hakki et al., 'A Dielectric Resonator Method of Measuring Inductive Capacities in the Millimeter Range', IRE Trans. on Microwave Theory and Techniques, Vol.MTT-24, No.10, 1960
  12. Y. Kobayashi et al., 'Microwave Measurement of Dielectric Properties of Low-Loss Materials by the Dielectric Rod Resonator Method', IEEE Trans. on Microwave Theory and Techniques, Vol.MTT-33, No.7, 1985
  13. K. Wakino, 'Relations between Microwave Dielectric Losses and Microstructure on $(Zn,Sn)TiO_3$ Dielectric Ceramics', J. Jpn. Ceram., 88(8), pp.475-482, 1980
  14. T. Hirata et al., 'Vibrational Spectroscopy and X-Ray Diffraction of Perovskite Compounds $Sr_{1-x}M_xTiO_3(M=Ca,\;Mg:\;0{\le}x{\le}1)$', J. Solid State Chem., Vol.124, pp.353-359, 1996 https://doi.org/10.1006/jssc.1996.0249
  15. E. Nagata, J. Tanaka, M. Tsutumi and E. Bannai, 'Distribution of Calcium Ion in the Crystal of $MgTiO_3-CaTiO_3$ System', Bul. Chem. Soc. Jpn., Vol.56, pp.3173-3174, 1983 https://doi.org/10.1246/bcsj.56.3173
  16. K. Tatsuki, 'Dielectric Properties of $PbO-ZrO_2-REOX$ Ceramics at Microwave Frequency', Jpn. J. Appl. Phys., Vol.26(Suppl. 26-2), pp.80-82, 1987