Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Thermodynamic and Electrical Properties of Aminophenol and Anthranilic Acid Complexes with Some Transition Metals

  • M. G. Abd El Wahed ;
  • S. M. Metwally ;
  • M. M. El Gamel ;
  • S. M. Abd El Haleem
  • Published : 20010700
Download PDF
⟨ Previous Next ⟩

Abstract

Thermodynamic and electrical functions of aminophenol and anthranilic acid complexes with Mn(Ⅱ), Fe(Ⅱ), Co(Ⅱ), Ni(Ⅱ) and Cu(Ⅱ) were determined. ΔG°, ΔH° and ΔS° were calculated with the help of stability constant values at different temperatures. It was found that the complexing processes have an exothermic nature. The studied complexes behave like semiconductors. The conduction takes place according to hopping mechanism. To show the composition of complexes conductometric and photometric titrations, IR spectra, thermal analysis and X-ray diffraction techniques were employed.

Keywords

References

  1. Bol. Soc. Quim. Peru. v.64 Abd El-Wahed, M. G.; Selim, S. R.; Seliman, S. A.; El Gamel, M. M.
  2. Can. J. Anal. Soc. Spectrosc. v.43 Abd El-Wahed, M. G.; Metwally, S. M.; El Manakhly, K. A.; Hammad, H. A.
  3. Bull. Korean Chem. Soc. v.18 Abd El-Wahed, M. G.; El Manakhly, K.; El Khososy, N.; El Farargy, A.
  4. Mater. Chem. Phys. v.47 Abd El-Wahed, M. G.; Metwally, S. M.; El Manakhly, K. A.
  5. Pol. J. Appl. Chem. v.36 Bartnik, R.; Strzyzewski, W.
  6. Boseikanri v.38 Yokota, H.
  7. Sb. Tr. Akad. Nauk Az. SSR Inst. Neftekkim. Protsessovim. Akad. Yu. G. Mamedalieva v.14 Musev, G. T.; Alimamdov, G. G.; Talibov, A. G.
  8. J. Med. Chem. v.19 Sorenson, T. R.
  9. Indian J. Chem. v.6 Shukla, P. R.
  10. Anorg. Allg. Chem. v.375 Achermann, G.; Hesse, D. Z.
  11. Indian J. Chem. v.25 Naraynana, G. V.; Swamy, S. J.; Lingaiah, P.
  12. Vapr. Kim-Kim. Teknol. v.94 Serebritskaya, L. F.; Lagachev, V. A.
  13. Zh. Neorgan. Khim v.10 Alyaviya, M. K.; Tephyakova, Z. M. Zh.
  14. Handbook of Advanced Materials Testing(Cheremisinoff, N. P., Cheremisinoff, P. N., Eds.) Abd El-Wahed, M. G.
  15. Physical Inorganic Chemistry, A Coordination Chemistry Approach Kettle, S. F. A.
  16. Inorg. Nucl. Chem. v.43 Murakami, S.; Yoshino, T. J.
  17. Can. J. Anal. Sci. Spectrosc. v.44 Abd El-Wahed, M. G.; Barakat, A. E.; Metwally, S. M.; Amer, A. M.
  18. Instrumental analysis Bauer, H. H.; Christian, G. D.; O’Reilly, J. E.
  19. Gazz. Chim. Italiana v.127 Abd El-Wahed, M. G.; Metwally, S. M.; El Gamel, M. M.; Abd El Haleem, S. M.
  20. Analytical Application of Complex Equlibria Inczedy J.
  21. Inorg. Nucl. Chem. v.29 Shukla, P. R. J.
  22. Anal. Chem. v.35 Dinsel, D. L.; Sweet, T. R.
  23. Thermochim. Acta v.228 Allan, J. R.; Paton, A. D.
  24. Electrical transport in solids Kao, K. C.; Hwang, W.