Bulletin of the Korean Chemical Society

  • 제22권11호
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  • Pages.1183-1191
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  • 2001
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Synergistic Effect on the Photocatalytic Degradation of 2-Chlorophenol Using $TiO_2$Thin Films Doped with Some Transition Metals in Water

  • 발행 : 20011100
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초록

The metallorganic chemical vapor deposition (MOCVD) method has been used to prepare TiO2 thin films for the degradation of hazardous organic compounds, such as 2-chlorophenol (2-CP). The effect of supporting materials and metal doping on the photocatalytic activity of TiO2 thin films also has been studied. TiO2 thin films were coated onto various supporting materials, including stainless steel cloth(SS), quartz glass tube (QGT), and silica gel (SG). Transition metals, such as Pd(II), Pt(IV), Nd(III) and Fe(III), were doped onto TiO2 thin film. The results indicate that Nd(Ⅲ) doping improves the photodegradation of 2-CP. Among all supporting materials studied, SS(37 ${\mu}m)$ appears to be the best support. An optimal amount of doping material at 1.0 percent (w/w) of TiO2-substrate thin film gives the best photodegration of 2-CP.

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참고문헌

  1. Chem. Rev. v.95 Hoffman, M. R.;Martin, S. T.;Choi, W.;Bahnenann, D. W.
  2. Photocatalytic Purification and Treatment of Water and Air Ollis, D. F.;Al-Ekabi, H.
  3. Proceedings of NATO Advanced Research Workshop on Homogneous and Heterogeneous Photocatalysis
  4. Chem. Rev. v.93 Fox, M. A.;Dulay, M. T.
  5. Environ. Eng. v.125 Suri, R. P. S.;Crittenden, J. C.;Fellow, P. E.;Hand, D. W.
  6. Environ. Sci. Technol. v.30 Peill, N. J.;Hoffman, M. R.
  7. J. Photochem. Photobiol. A v.98 Litter, M. L.;Navio, J. A.
  8. Solar Energy Materials and Solar Cells v.62 Murata, Y.;Fukuda, S.;Ishikikawa, S.;Yokoyama, S.
  9. J. Mater. Sci. v.34 Wang, Y.;Cheng, H.;Hao, Y.;Ma, J.;Li, W.;Cai, S.
  10. US Patent 4, 303, 486 Bard, A. J.;Bernhard, K.
  11. App. Cat. B.:Environ. v.7 Fernandez, A.;Lassaletta, G.;Jimenez, V. M.;Justo, A.;Gonzales, A. R.;Herrmann, J. M.;Tahiri, H.;Ait-Ichou, Y.
  12. J. Environ. Eng. Roberto, J. C.;Walter, A. Z.;Anderson, A.
  13. App. Cat. B:Environ v.17 Byme, J. A.;Eggins, B. R.;Brown, N. M. D.;McKinney, B.;Rouse, M.
  14. Catalysis Today v.39 Zakharenko, V. S.
  15. Catalysis today v.51 Xingtao, G.;Israel, E. W.
  16. Catalysis Today v.40 Leyva, E.;Moctezuma, E.;Ruiz, M. G.;Torres-martinez, L.
  17. Environ. Eng. Ha, H. Y.;Anderson, M. A
  18. Applied. Catalysis B: Environ v.23 Zorn, M. E.;Tompkins, D. T.;Zeltner,W. A.;Anderson, M. A
  19. J. Phys. Chem. B v.102 Ranjit, K. T.;Willner, I.;Bossmann, S.;Braun, A.
  20. Langmuir v.16 Ding, Z.;Hu,X.;Lu, G. Q.;Yue, P. L.;Greenfield, P. F.
  21. Applied Catalysis A:General v.178 Navio, A. J.;Testa, J. J.;Djedjeian, P.;Padron, J. R.;Rodriguez, D.;Litter, M. I.
  22. J. Vac, Sci. Technol. A v.15 Guerin, D.;Saha, S. I.
  23. Chem. Vap. Deposition v.5 Battiston,G. A.;Gerbasi, R.;Porchia, M.;Gasparotto, A.
  24. J. Am. Ceram. Soc. v.82 Krumdieck, J. S.;Raj, R.
  25. Eur. J. Inorg, Chem. v.202 Chemseddine, A.;Moriz, T.
  26. Anal. Chem. v.29 Spurr, A. R.;Myers, M.
  27. Photochem. Photobiol.A:Chem. v.56 Sclafani, A.;Palmisano, E.;Davi, E.
  28. J. Photochem. Photobiol.A:Chem. v.79 Vidal, A.;Herrero, J.;Romero, M.;Sanchez, B.;Sanchez, M.
  29. Handbook of X-ray Photoelectron Spectroscopy Wagner, C. D.(ed.)
  30. J. Electrochem. Soc. v.142 Toda, H.;Honda, H.
  31. Applied Cat. B:Environ v.7 Fernandez, A.;Lassaletta, G.;Jimenez, V. M.;Justo,A.;Gonalez-Elipe, A.;Herrmann, J.-M.;Tahiri, H.;Ait-Ichou, Y.
  32. Applied Catlysis A:General v.178 Jose, A. N.;Juan, J. T.;Pablo, D.;Javier, R. P.;Dina, R.;Marta, I. L.
  33. Material Res. Bulletin v.33 Sawunyama, P.;Yasumori, A.;Okada, K.
  34. J. Phys. Chem. v.94 Gratzel,M.;Howe, R. F.
  35. Environ. Sci. Technol v.28 Yin, Z.;John, C. C.;David, W. H.;David, L. P.
  36. Wat. Sci. Tech. v.23 Tseng, J. M.;Huang, C. P.
  37. Chemosphere Jung, O. J.;Sung, M.;Huang, C. P.

피인용 문헌

  1. Photoinduced reactivity of titanium dioxide vol.32, pp.1, 2001, https://doi.org/10.1016/j.progsolidstchem.2004.08.001
  2. Prediction of Hydroxyl Substitution Site(s) of Phenol, Monochlorophenols and 4-Chloronitrobenzene by Atomic Charge Distribution Calculations vol.30, pp.4, 2001, https://doi.org/10.5012/bkcs.2009.30.4.787
  3. CVD Production of Doped Titanium Dioxide Thin Films vol.18, pp.4, 2001, https://doi.org/10.1002/cvde.201200048