인산염 표면 조정액 중의 킬레이트제 첨가 영향

Effects of the addition of chelate compound in phosphating surface conditioning solution

Phosphating treatments have been performed to improve paint adhesion and corrosion resistance of zinc and zinc alloy coated steels for a long time. In this work, the effects of the addition of chelate compound were studied to improve the stability of surface conditioning solution and properties of zinc phosphate films. The coalescence of colloidal Ti-compound and extraneous charged particles (alkaliearth metal cation such as $Mg^{2+}$ , $Ca^{2+}$ ) were suppressed by using a surface conditioning solution with chelate compound. Therefore, after surface conditioning solution containing chelate compound was left standing for one week at room temperature, the formation of a white sediment was decreased comparing to surface conditioning solution without chelate compound. The crystal size of phosphate film was fine and the whiteness value of phosphated zinc coated steel sheets was also high without the decrease of corrosion resistance and anti-patina. It was very effective to use chelate compound improving the stability of surface conditioning solution.