한국염색가공학회지 (Textile Coloration and Finishing)

  • 제13권3호
  • /
  • Pages.188-196
  • /
  • 2001
  • /
  • 1229-0033(pISSN)
  • /
  • 2234-036X(eISSN)
한국염색가공학회 (The Korean Society of Dyers and Finishers)
권호 표지

포스파젠 유도체에 의해 경화된 에폭시수지의 내수.내약품성

Resistance to Chemicals and Water of Epoxy Resin Cured with Phosphazene Derivatives

  • 윤흥수 (경일대학교 공과대학 섬유패션학과) ;
  • 최경식 (경일대학교 공과대학 섬유패션학과)
  • 발행 : 2001.06.01
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초록

1, 1-diamino-3, 3, 5, 5-tetrachlorocyclotriphosphazene, 1, 1-diami-no3, 3, 5, 5-tetra-(p-bromophenoxy)cyclotriphosphazene, and 1, 1-diamino-3, 3, 5, 5-tetra-(p-chlorophenoxy) cyclotri-phosphazene(ACPP) was prepared from hexachlorocyclotriphosphazene and used for the curing agent of bisphenol A type epoxy resin and phenol novolak. The resistance to chemicals and water of the cured epoxy resins were examined by DMTA and compared with those of the epoxy rosins cured with phosphazene derivatives and 4, 4'-diaminodiphenylmethane. The effect of the curing agent on resistance to chemicals and water of the cured epoxy resins were investigated. The epoxy resins cured with 1, 1-diamino-3, 3, 5, 5-tetrachlorocyclotriphosphazene and 1, 1- diamino-3, 3, 5, 5-tetra- (p-bromophenoxy)cyclotriphosphazene showed superior resistance to chemicals and water to those of 1, 1-diamino-3, 3, 5, 5-tetra- (p-chlorophenoxy)cyclotriphosphazene and 4, 4'-diaminodiphenylmethane. It is an effective curing agent for epoxy resins to enhance the resistance to chemicals, water and tome proofing.

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