A Study of Hydrogen Embrittlement Limit Potential of Cu-Containing High Strength Low Alloy Steel for Marine Structure by Potentiostatic SSRT Method

정전위 SSRT법에 의한 해양구조물용 Cu함유 고장력저합금강의 수소취성한계전위 규명에 관한 연구

  • 김성종 (일본 나고야대학 이공과학종합 연구센터) ;
  • 박태원 (국방과학연구소) ;
  • 심인옥 (국방과학연구소) ;
  • 김종호 (한국해양대학교 기관시스템공학부) ;
  • 김영식 (한국해양대학교 기계소재공학부) ;
  • 문경만 (한국해양대학교 기계소재공학부)
  • Published : 2001.04.01

Abstract

A marine structural material was well known to have high tensile strength, good weldability and proper corrosion resistance. Cu-containing high strength low alloy(HSLA) steel was recently developed for their purposes mentioned above. And the steel is free about preheating for welding, therefore it is reported that shipbuilding cost by using it can be saved more or less. However the marine structural materials like Cu-containing HSLA steel are being generally adopted with cathodic protection method in severe corrosive environment like natural sea water but the high strength steel may give rise to Hydrogen Embrittlement due to over protection at high cathodic current density for cathodic protection. In this study Cu-containing HSLA steel using well for marine atructure was investigated about the susceptibility of Hydrogen Embrittlement as functions of tensile strength, strain ratio, fracture time, and fracture mode, etc. and an optimum cathodic protection potential by slow strain rate test(SSRT) method as well as corrosion properties in natural sea water. And its corrosion resistance was superior to SS400 steel, but Hydrogen Embrittlement susceptibility of Cu-containing HSLA steel was higer than that of SS400 steel. However Hydrogen Embrittlement of its steel by SSRT method was showed with pheonomena such as decreasing of fracture time, strain ratio and fracture mode of QC(quasi-cleavage). Eventually it is suggested that an optimum cathodic protection potential not presenting Hydrogen Embrittlement of Cu-containing of HSLA steel by SSRT method was from-770mv(SCE) to - 900mV(SCE)under natural sea water.

Keywords

References

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