Korean Journal of Crystallography (한국결정학회지)

Korean Crystallographic Association (한국결정학회)
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Synthesis and Structure of trans-Dichlorobis(diisopropylaniline) palladium(II), trans-$[Pd(NH_2-C_6H_3-2, 6-i-Pr_2)_2Cl_2]$

trans-Dichlorobis(diisopropylaniline) palladium(II), trans-$[Pd(NH_2-C_6H_3-2, 6-i-Pr_2)_2Cl_2]$의 합성 및 구조

  • Hye Jin Kim (Department of Chemistry, Sungkyunkwan University) ;
  • Won Seok Han (Department of Chemistry, Sungkyunkwan University) ;
  • Soon Won Lee (Department of Chemistry, Sungkyunkwan University)
  • Published : 2001.09.01
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Abstract

Compound PdCl₂(Phc≡N)₂(1) reacted with 2,6-diisopropylaniline to give trans-[Pd(NH₂-C/sub 6/-H₃-2, 6-i-Pr₂)₂Cl₂] (2). Compound 2 was characterized by spectroscopy (¹H-NMR, /sup 13/C-NMR, and IR) and X-ray diffraction. Crystallographic data for 2: monoclinic space group P2₁/n, a=13.532(3) Å, b=5.749(1) Å, c=17.880(4)Å, β=103.84(2)°, Z=2, R(wR₂)=0.0466(0.1226).

화합물 PdCl₂(PhC≡N)₂(1) 와 2.6-diisopropylaniline 이 반응하여 trans-[Pd(NH₂-C/sub 6/-H₃-2, 6-i-Pr₂)₂Cl₂] (2)가 합성하였다. 화합물 2의 구조가 분광학적 방법(¹H-NMR, /sup 13/C-NMR, IR) 및 X-ray 회절법으로 규명되었다. 화합물 2의 결정학 자료: 단사정계 공간군 P2₁/n, a=13.532(3)Å, b=5.749(1)Å, c=17.880(4)Å, β=103.84(2)°, Z=2, R(wR₂)=0.0466(0.1226).

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