The Synthesis of Ti-37.5at%Si Powders by MA and Their Sintering Characteristics

기계적 합금화에 의한 Ti-37.5at%Si 분말의 합성 및 소결 특성

  • 이상호 (한밭대학교 재료공학전공) ;
  • 변창섭 (한밭대학교 재료공학전공) ;
  • 김동관 (한밭대학교 재료공학전공)
  • Published : 2001.12.01

Abstract

Ti-37.5at%Si elemental powder mixtures were mechanically alloyed by a high-energy ball mill, followed by CIP (cold isostatic pressing) and HIP (hot isostatic pressing) for different processing conditions. Only elemental phases (Ti and Si) were observed for the 5 min mechanically alloyed (MA 5 min) powder, but only $Ti_5Si_3$phase was observed for the 30 min mechanically alloyed (MA 30 min) powder. $Ti_5Si_3$phase was observed for the HIPed compact of MA 5 min and 30 min powders at 150 and 190 MPa for 3 hr at $1000^{\circ}C$. For the HIPed compacts, the highest sintered density was obtained to be 99.5% of theoretical density by a HIP step at $1350^{\circ}C$ at 190MPa for 3hr. The hardness values of the HIPed $Ti_5Si_3$compacts at $1350^{\circ}C$ at 150/190 MPa for 3hr were higher than HRC 76. The densification and mechanical property of HIPed $Ti_5Si_3$compacts was found to depend on more HIP temperature than HIP pressure.

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