Emission Properties of Electro luminescent Devices using Poly(3-hexylthiophene) Deposited by LB Method

LB법으로 첨가한 Poly(3-hexylthiophene)을 발광층으로 사용한 전계발광소자의 발광특성

  • 김주승 (전남대학교 전기공학과) ;
  • 이경섭 (동신대학교 전기전자공학부) ;
  • 구할본 (전남대학교 전기공학과)
  • Published : 2001.09.01

Abstract

We studied emitting properties of organic electroluminescent devices fabricated using the spin-coating and Langmuir-Blodgett(LB) technique. The LB technique has the advantage of precise control of the thickness better than spin-coating method. LB monolayer of poly(3-hexylthiophene)(P3HT) was deposited 27 layers onto the indium-tin-oxide(ITO) substrate as Y-type films by the vertical dipping method. In the absorption spectra, the λ$\_$max/ of P3HT-AA LB films and of spin-coating films showed about at 510, 545 and 590 nm corresponding to 2.43, 2.28, 2.10eV. And we observed that the turn-on voltage of devices deposited by LB method(10V) was higher than that of spin-coating method(8.5V) in voltage-current-luminance characteristic. In the logV-logJ characteristics of ITO/P3HT-AA LB/Al device, we confirmed that El device fabricated by LB method follows three conduction mechanisms: ohmic, space-charge-limited current(SCLC) conduction and trapped-carrier-limited space-charge current(TCLC) conduction.

Keywords

References

  1. Appl. Phys. Lett. v.51 no.12 Organic electroluminescent diodes C. W. Tang;S. A. VanSlyke
  2. 전기전자재료학회논문지 v.12 no.10 Poly(9,9-dihexadecyfluorene)을 이용한 유기 Electroluinescent Display용 녹색 발광소자 개발에 관한 연구 구할본;김주승;서부완;古野勝美
  3. Appl. Phys. Lett. v.69 no.15 Organic electroluminescent device with improved stability S. A. Van Slyke;C. H. Chen;C. W. Tang
  4. Synth. Met. v.99 Langmuir-Blodgett light-emitting diodes of poly(3-hexylthiophene):electrooptical characteristics related to structure T. Ostergard;J. Paloheimo;A. J. Pal;H. Stubb
  5. 전기전자재료학회논문지 v.12 no.11 유기 박막의 자격 전달에 관한 연구 조수영;김성진;강용철;이경섭;岩本光正
  6. Macro molecules v.30 no.24 Regiocontrolled Synthesis of Poly((3-hexylthiophene-ylene)ethynylenes):Their Characterization and Photolumine scent Properties Juan Li;Yi Pang
  7. 膜 v.11 no.3 LB膜とエレクトロニクス 杉道夫
  8. Thin Solid Films v.273 High conducting Langmuir-Blodgett films comprising head-to-tail poly(3-hexylthiophene) M. Rikukawa;M. Nakogawa;K. Ishida;H. Abe;K. Sanui;N. Ogata
  9. Semiconductors and semimetals v.64 V. Bulovic;P. E. Burrows;S. R. Forrest
  10. 한국전기전자재료학회 추계 학술대회 논문집 란탄계 금속 착화합물을 이용한 다양한 유기 전기발광소자의 연구 표상우;이한성;이승희;김영관;김정수
  11. 한국전기전자재료학회 춘계학술대회 논문집 Poly(3-hexylthiophene) 전계발광소자에 도입된 alkyl side chain의 길이에 따른 발광특성 서부완;김주승;구할본