Electrical Properties of Polyaniline according to Preparation Conditions

제조 조건에 따른 Polyaniline의 전기적 성질

  • 김언령 (고려대학교 재료공학과) ;
  • 김태영 (고려대학교 재료공학과) ;
  • 이보현 (고려대학교 재료공학과) ;
  • 김종은 (고려대학교 공학기술 연구소) ;
  • 서광석 (고려대학교 재료공학과) ;
  • 배종현 (경희대학교 화학공학과)
  • Published : 2001.03.01

Abstract

Polyaniline-Camphorsulfonic Acid Emeraldine Salt(PANI-CSA ES) was prepared by doping Polyaniline Ermeralidine Base(PANI EB) with DL-10-Camphorsulfonic Acid(CSA). PANI-CSA ES was solved in an organic solvent by ultrasonification for different periods of time and its surface resistivity was measured. Several PANI-CSA ES solutions solved in different organic solvents were prepared and their surface resistivities were measured. Thermal stability of film casted with PANI-CAS ES solution in m-cresol was estimated by measuring its surface conductivity and the content of this moisture and organic solvents. PANI-CSA ES was blended with different polymeric binders to improve its physical properties and the surface resistivities of several kinds of PANI-CSA ES blends were measured as a function of the content of PANI-CSA ES. PANI-CSA ES polymerized by 1-step oxidative polymerization was prepared and its surface resistivity was measured.

Keywords

References

  1. Synth. Met. v.79 Thermal Stability of Polyaniline Networks in Conducting Polymer Blends C. Y. Yang(et. al.)
  2. Synth. Met. v.48 Counter-ion Induced Processibility of Conducting Polyaniline and of Conducting Polyblends of Polyaniline in Bulk Polymers Y. Cao(et. al.)
  3. Synth. Met. v.85 Thin Polyaniline Films in EMI Shielding T. Makela(et. al.)
  4. J. KIEEME v.10 no.1 Eletrical and Electromagnetic Shielding Properties of Polyaniline Films with Different Degrees of Crosslinking J. W. Kim
  5. J. KIEEME v.11 no.1 Electrical Conductivity and Electromagnetic Interference Shielding Characteristics of Polyaniline Films with Adding Material J. W. Kim
  6. J. KIEEME v.13 no.1 Preparation and Characteristics of Transparent Anti-static Films J. E. Kim(et. al.)
  7. Chemworld v.33 no.5 Conducting Polymer: Polyaniline E. J. Oh
  8. Synth. Met. v.69 Effect of Solvents and Co-sovents on the Processibility of Polyaniline:Ⅰ/ Solubility and Conductivity studies Y. Cao(et. al.)
  9. Appl. Phys. Lett. v.60 no.22 Solution-cast Films of Polyaniline:Optical-quality Transparent Electrodes Y. Cao(et. al.)
  10. Final Report: Development of EMI Shielding Technique for Electronic Equipments using Transparent Conductive Polymers K. S. Suh(et. al.)
  11. Electrical and Optical Polymer Systerms D. L. Wise(et. al.)
  12. Synth. Met. v.69 Secondary Doping in Polyaniline A. G. Macdiarmid(et. al.)