A Study on Natural Dyeing (3) - Change of physical structure and Chinese gallotannin treatment on silk fabric -

천연염색에 관한 연구 (3) - 견에 대한 Chinese gallotannin 처리 및 구조변화 -

  • Published : 2001.10.01

Abstract

As the basic study to investigate the mechanism of improvement in the dyeing fastness of natural dyes on silk fabrics the optical behavior of tannin solution, the optimal condition of tannin treatment and the changes of the physical structure of silk fabrics were studied in the treatment of tannin. Results obtained were as follows ; 1.The K/S values of tannin-treated silk fabrics were not changed by tannin content on silk fabrics but yellowing of tannin in treatment condition. 2. As the concentration of tannin was increased in its treating condition, the tannin content and K/S vague of tannin-treated silk fabrics were increased. 3. Because tannin gave rise to yellowing by hydrolysis and oxidation at high temperature, the higher tannin-treating temperature was, the lower the tannin content and K/S values of silk fabrics 4. The tannin content of silk fabric was higher in acidic treating condition and the highest K/S value was showed at pH 5. 5. As the tannin content of silk fabric was increased, the value of ζ -potential of it became negative. 6. As the tannin content of silk fabric was increased, the crystallinity and crystallite size of it were decreased. This meant that the fraction of amorphous region in the fibers increased. And the degree of orientation of it was decreased with the tannin treatment.

Keywords

References

  1. Dyeing Industry v.33 no.7 Motoi Minagawa
  2. Korean J. Seric. Sci. v.28 no.1 I.M.Chung;Y.W.Lee;K.E.Song
  3. Sen-i Gakkaishi v.32 no.3 Shinji Ogasawara;Toshio Kato;Shigetaka kuroiwa
  4. Sein-i Gakkaishi v.34 no.5 Shinji Ogasawara;Masayasu Ishiyama;Shigetaka kuroiwa
  5. Sen-i Gakkaishi v.38 no.1 Shinji Ogasawara;Kenichi Ito;Kazuhiko Yanagi;Shigetaka kuroiwa
  6. Sen-i Gakkaishi v.37 no.8 Shinji Ogasawara;Sadayuki Takino;Takieshi Hosoya;Shigetaka kuroiwa
  7. JSDC v.1 J. Shore
  8. Sen-i Gakkaishi v.26 no.5 Shinji Ogawawara;Shigetaka kuroiwa
  9. Sen-i Gakkaishi v.36 no.12 Shinji Ogasawara;Yoshio Amari;Shigetaka kuroiwa
  10. Sen-i Gakkaishi v.37 no.6 Shinji Ogasawara;Hiromasa Asami;Yoshifumi Kimura;Shigetaka kuroiwa
  11. Journal of Colloid and Interface Science v.202 A. Ontiveros-Ortega;M. Espinosa-Jimenez;E. Chibowski;F. Gonzalez-Caballero
  12. Journal of Colloid and Interface Science v.207 M. Espinosa-Jimenez;E. Gimenez-Martin;A. Ontiveros-Grtega
  13. Sen-i Gakkaishi v.38 no.5 Shinji Ogasawara;Shuji Kurooka;Makoto Koizumi;Shigetaka kuroiwa
  14. Sen-i Gakkaishi v.31 no.4 Shinji Ogasawara;Takao Seki;Shigetaka kuroiwa
  15. JJ. of the Korean Soc. of Dyers and Finishers v.7 no.3 Jung Hwa Sul;Suk Choi;Kyung Rae Cho
  16. J. of the Korean Soc. of Dyers and Finishers v.6 no.1 Jung Hwa Sul;Suk Chul Choi
  17. Journal of the Korean Society of Dyers and Finishers v.6 no.4 In Young Kim
  18. Dyeing Industry v.37 no.5 Mitsuo Kimura
  19. Economics of Japan v.41 no.5 Mitsuo Kimura;Tetsuo Nakajima;Yoshiaki Shimizu
  20. 천연염색의 색상다양화 및 염색 견뢰도 향상 기술 개발 산업자원부
  21. J. of the Korean Soc. of Dyers and Finishers v.13 no.1 H. I. Kim;S.I.Eom;S.M.Park
  22. Biochem.J. v.139 Haslam E.
  23. Methods Enzymol v.31 Loomis W.D.
  24. Recent Adv. Phytochem v.12 Haslam E.
  25. J. Agric. Food Chem. v.28 Hagerman A.E.;Butler L.G.
  26. 植物色素 林孝三
  27. Journal of Photochemistry and Photobiology B; Biology v.33 R.S.Davidson
  28. American Dyestuff Reporter v.1 Yutaka Kawahara
  29. Sen-i Gakkaishi v.42 no.9 Izumi Fumoto
  30. J. of the Korean Soc. of Dyers and Finishers v.6 no.2 K. R. Cho
  31. J. Korean Soc. of Dyers and Finishers v.28 no.8 S. S. Kim;N. S. Kim