Adsorption Characteristics of Heavy Metals in Wastewater on Bone Charcoal

Bone Charcoal에 의한 폐수증의 중금속 흡착특성

  • 정팔진 (전북대학교 환경공학과) ;
  • 곽동희 (서남대학교 환경공학과) ;
  • 이재욱 (서남대학교 화학공학과)
  • Published : 2000.12.30

Abstract

The study was conducted to evaluate the adsorption equilibrium of heavy metals on bone charcoal made of livestock bone which was sintered at $550{\sim}600^{\circ}C$. Analysis of bone charcoal by XRD and FT-IR showed that crystal structure was similar to that of synthetic hydroxyapatite. Adsorption equilibrium capacity of single component (Pb, Cd, and Zn) on bone charcoal could be expressed as Langmuir, Freundlich, and Sips equations. Sips isotherm was best among the three isotherms. The values predicted by IAST(ideal adsorbed solution theory) showed good relationship to the experimental data in multicomponent adsorption equilibrium. Adsorption affinity was in order of Pb, Cd, and Zn. The order was same in case of activated carbon or synthetic hydroxyapatite. Through the study results. it would be expected that bone charcoal made of livestock could be used in field of wastewater treatment plants as adsorbent to remove heavy metal.

Keywords

References

  1. Gas Separation by Adsorption Processes Yang,R.T.
  2. Principles of Adsorption and Adsorption Processes Ruthven,D.M.
  3. 화학공학 v.37 no.6 활성탄에 대한 말토올리고당의 흡착평형 이재욱;정흥조;문희;문일식
  4. Adsorption v.5 Effect of pH on Adsorption of Cephalosporin C by a Nonionic Polymeric Sorbent Lee,J.W.;Moon,H.
  5. Separation and Purification Tech. v.12 Adsorption and Desorption of Cephalosporin C on Nonionic Polymeric sorbents Lee,J.W.;Park.H.C.;Moon,H.
  6. Korean J.of Chem.Eng. v.14 no.4 Effect of Operating Conditions on Adosrption of Cephalsoporin C in a Column Adsorber Lee,J.W.;Jung,H.J.;Moon,H.
  7. Korean J.Chem.Eng. v.15 no.8 Performance Evaluation of Carbon Adsorbents for Automobile Canisters Shim,W.G.;Lee.J.W.;Moon,H.
  8. J.Am.Chem.Soc. v.40 The Adsorption of Gases on Plane Surfaces of Glass, Mica and Platinum Langmuir,I.
  9. Colloid and Capillary Chemistry(3rd German Edn) Freundlich,H.
  10. J.Chem.Phys. v.18 On the Surface of a Catalyst Surface Sips,R.J.
  11. Adsorption of Gases on Heterogeneous Surfaces Rudzinski,W.;Everett,D.H.
  12. AIChE J. v.11 Thermodynamics of Mixed Gas Adsorption Myers,A.L.;Prausnitz,J.M.
  13. AIChE J. v.26 A Gas Adsorption Isotherm Equation Based on Vacancy Solution Theory Suwanayuen,S.;Danner,R.P.
  14. Powder Surface Area and Porosity Lowell,S.;Shields,J.E.