(National Institute of Environmental Research)
(국립환경연구원)
This analysis was conducted for PCDDs/PCDFs in sediment by isotope dilution HRGC/HRMS method. From the result, the mean recovery of surrogate standard was in the range of 70.1-80.8%. Among the distribution of 2, 3, 7, 8-substituted isomers, the concentration of OCDD represented almost 40.6-78.5% of total concentration and that of OCDF showed 6.6-14.7% and 1, 2, 3, 4, 6, 7, 8-HpCDD showed 5.1-7.7%. The portion of PCDDs represented 62.4-86.9% of total PCDDs/PCDFs. In the TEQ concentration 1, 2, 3, 4, 7, 8-PeCDF concentration represented 22.7-35.6 % of total TEQ concentration.
본 연구에서는 isotope dilution HRGC/HRMS 방법으로 저니토중의 PCDDs/PCDFs를 분석하였다. 분석결과 surrogate 표준물질의 평균 회수율은 70.1-80.8%로 양호하였다. 17종의 2, 3, 7, 8-치환이성체 분포에서는 OCDD가 총 농도의 40.6-78.5%를 나타내었으며, OCDF는 6.6-14.7%, 1, 2, 3, 4, 6, 7, 8-HpCDD는 5.1-7.7%를 나타내었다. 또한 PCDDS가 총 PCDDs/PCDFs중 62.4-86.9%를 나타내었다. TEQ 농도분포에서는 2, 3, 4, 7, 8-PeCDF가 22.7-35.6%를 나타내었다.