Bulletin of the Korean Chemical Society

  • 제21권8호
  • /
  • Pages.785-792
  • /
  • 2000
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  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Electron Impact Fragmentations of Chlorinated Organophosphorus Pesticides

  • 발행 : 20000800
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초록

Mass spectral fragmentations of six chlorinated organophosphorus pesticides were investigated using electron impact mass spectrometry. Understanding the fragmentation pathways, based on the fragment ions of mass spectra, should be useful in the structural elucidation and chemical identification of these compounds. The pro-posed fragmentation pathways were verified by collision-induced dissociation B/E-linked scan spectra. ln most cases,the structures of characteristic fragment ions could be expected by the observation of the peak clusters due to 35Cl and 37Cl isotopes. According to substituted groups on phosphorus atom, phosphate and phospho-rothioate exhibited significantIy differentfragmentation patterns. Especially, phosphate and phosphorothioate with diethyl ester produced more diverse fragment ions than that with dimethyl ester.

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참고문헌

  1. J. Assoc. Off. Anal. Chem. v.70 Roach, J. A.;Carson, L. J.
  2. J. Chromatogr. v.639 Hong, J.;Eo, Y.;Rhee, J.;Kim, T.;Kim, K.
  3. Environ. Sci. Technol. v.22 Betowski, L. D.;Jones, T. L.
  4. J. Assoc. Off. Anal. Chem. v.49 Damico, N. J.
  5. Anal. Chem. v.59 Swackamer, D. L.;Charles, J.;Hites, R. A.
  6. J. Am. Soc. Mass Spectrom. v.7 Kuivalainen, T.;Kostiainen, R.;Uggla, R.;Sundberg, M. R.;Bjork, H.
  7. Mass Spectrom. Rev. v.2 Yost, R. A.;Fetterolf, D. D.
  8. Rapid Commun. Mass Spectrom. v.13 Hong, J.;Shin, C.-M.;Kim, Y. H.;Yoo, J. S.
  9. Org. Mass Spectrom. v.21 Hummel, S. V.;Yost, R. A.
  10. J. Mass Spectrom. v.34 Keck, H.;Tommes, P.
  11. J. Am. Chem. Soc. v.106 Yates, B. F.;Bouma, W. J.;Radom, L.
  12. J. Am. Chem. Soc. v.114 Zeller, L.;Farrell, Jr. J.;Vainiotalo, P.;Kenttamaa, H. I.
  13. J. Off. Anal. Chem. v.57 Holmstead, R. L.;Casida, J. E.
  14. Org. Mass Spectrom. v.3 Pritchard, J. G.

피인용 문헌

  1. Collision-Induced Intramolecular Energy Flow in Highly Excited Toluene vol.24, pp.8, 2000, https://doi.org/10.5012/bkcs.2003.24.8.1223