Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Photopolymerization of Methyl Methacrylate with 1,4-$C_6H_4(SiH_{3-x}Me_x)_2$

  • Published : 20000300
Download PDF
⟨ Previous Next ⟩

Abstract

The bulk photopolymerization of methyl methacrylate(MMA) with bis(silane)s such as 1,4-$C_6H_4(SiH_3)_2$ (1) and 1,4-$C_6H_4(SiH_2Me)_2$ (2) was performed to produce poly(MMA)s possessing the corresponding bis(silyl) moiety as an end group. For the bis(silane)s, while the polymerizaiton yields and the polymer molecular weights decreased, the TGA residue yields and the relative intensities of Si-H IR stretching bands increased as the relative bis(silane) concentration over MMA increased. The polymerizaion yield, polymer molecular weight, and TGA residue yield of MMA with 1 were found to be higher than those with 2. The bis(silane)s appears to influence significantly upon the photopolymerization of MMA as both chain initiation and chain transfer agents.

Keywords

References

  1. Principles of Polymerization(3rd ed.) Odian, G.
  2. Proc. Roy. Soc.(London) v.A251 no.4 Norrish, R. G.;Simons, J. P.
  3. Organometallics v.14 no.2672 Chatgilialoglu, C.;Ferreri, C.;Lucarini, M.;Pedrielli, P.;Pedulli, G. F.
  4. Organomet. Chem. v.400 no.81 Corriu, R. J. P.
  5. J. Am. Chem. Soc. v.114 no.7047 Woo, H.-G.;Walzer, J. F.;Tilley, T. D.
  6. Organometallics v.14 no.2415 Woo, H.-G.;Kim, S-Y.;Han, M.-K.;Cho, E. J.;Jung, I. N.
  7. Adv. Organomet. Chem. v.42 no.363 Gauvin, F.;Harrod, J. F.;Woo, H.-G.
  8. J. Am. Chem. Soc. v.120 no.12988 Shu, R.;Hao, L.;Harrod, J. F.;Woo, H.-G.;Samuel, E.
  9. Comprehensive Organometallic Chemistry v.2 Armitage, D. A.;Wilkinson, G.(ed.);Stone, F. G. A.(ed.);Abel, E. W.(ed.)
  10. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) v.34 no.1 Carothers, T. W.;Mathias, L.
  11. Organometallics v.13 no.2682 Seyferth, D.;Son, D. Y.;Rheingold, A. L.;Ostrander, R. L.
  12. J. Am. Chem. Soc. v.113 no.4043 Mathias, L. J.;Carothers, T. W.
  13. Poylm. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) v.34 no.1 Sun,F.;Grainger, D. W.
  14. Poylm. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) v.34 no.1 Lewis, C. M.;Mathias, L. J.
  15. Makromol. Chem. v.83 no.148 Greber, G.;Hallensleben, M. L.
  16. Organometallics v.10 no.1457 Boury, B.;Corriu, R. J. P.;Leclercq, D.;Mutin, P. H.;Planeix, J. M.;Vioux, A.
  17. Bull. Korean Chem. Soc. v.16 no.360 Hong, L.-Y.;Wo, H.-G.;Ham, H.-S.
  18. Bull. Korean Chem. Soc. v.16 no.774 Woo, H.-G.;Hong, L.-Y.;Kim, S.-Y.;Park, S.-H.;Song, S.-J.;Ham, H.-S.
  19. Bull. Korean Chem. Soc. v.17 no.16 Woo. H.-G.;Hong, L.-Y.;Park, J.-Y.;Jeong, Y.-T.;Park, H.-R.;Ham, H.-S.
  20. Macromolecules v.24 no.6863 Woo, .-G.;Walzer, J. F.;Tilley, T. D.
  21. Chem. Mater. v.5 no.1487 Imori, T.;Woo, H.-G.;Walzer, J. F.;Tilley, T. D.
  22. J. Am. Chem. Soc. v.109 no.5268 Kanabus-Kaminska, J. M.;Mawari, J. A.;Griller, D.
  23. J. Chem. Soc., Perkin Trans v.2 no.421 Ballestri, M.;Chatgilialoglu, C.;Guerra, M.;Guerrini, A.;Lucarini, M.;Seconi, G.
  24. Acc. Chem. Res. v.14 no.246 Walsh, R.
  25. Inorganic Chemistry: Principles of Structure and Reactivity(4rg ed.) Huheey, J. E.;Keiter, E. A.;Keiter, R. L.
  26. Polymer Handbook(3rd ed.) Brandrup, J.;Immergut, E. H.
  27. Ph.D. Thesis Woo, H.-G.
  28. Bull. Korean Chem. Soc. v.17 no.475 Woo, H.-G.;Song, S.-J.;You, H.;Cho, E. J.;Jung, I. N.
  29. Bull. Korean Chem. Soc. v.18 no.1264 Yang, S.-Y.;Park, J.-M.;Woo, H.-G.;Kim, W.-G.;Kim, I.-S.;Kim, D.-P.;Hwang, T.-S.
  30. J. Am. Chem. Soc. v.116 no.9779 Hsiao, Y.-L.;Waymouth, R. M.