Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Determination of Residual Monomers in Dental Pit and Fissure Sealants

  • Published : 20001100
Download PDF
⟨ Previous Next ⟩

Abstract

Specimens were cured by using a 1 mm (thickness) ${\times}$5 mm (diameter) teflon mold, and were immersed in artificial saliva and in 75% ethanol for 1, 7, 14, 21 and 28 days in order to quantify and to identify toxic components and to determine any degra dation byproducts of Bis-GMA that might be released from five commercially available resin-based dental sealants. In artificial saliva, the only released component was triethylene glycol dimethacylate (TEGDMA). In 75% ethanol, TEGDMA, 2,2-bis[4-(2-hydroxy-3-methacryloyloxypropoxy) phenyl]propane (Bis-GMA) and urethane dimethacrylate (UDMA) were released highly at the initial stage, indicating that the amount of component released is not linearly correlated with the immersion time. The amount of released TEGDMA was found to be much higher in 75% ethanol than in artificial saliva. Importantly, bisphenol-A (BPA) was detected from all the uncured sealants tested, suggesting that all the sealants tested contain BPA as a contaminant.

Keywords

References

  1. Eur. J. Oral Sci. v.106 Geurtsen, W.
  2. Chem. Commun. Mou, L.;Singh, G.;Nicholson, J. W.
  3. Eur. J. Oral Sci. v.105 Muller, H.;Olsson, S.;Soderholm, K-J.
  4. Science News v.149 Raloff, J.
  5. J. Biomed. Mater. Res. v.45 Schafer, T. E.;Lapp, C. A.;Hanes, C. M.;Lewis, J. B.;Wataha, J. C.;Schuster, G. E.
  6. J. Dent. Res. v.77 Hansel, C.;Leyhausen, G.;Mai, U.;Geurtsen, W.
  7. Biomaterials v.20 Shajii, L.;Santerre, J. P.
  8. J. Am. Dent. Assoc. v.130 Soderholm, K-J.;Phil, M.;Mariotti, A.
  9. Scan. J. Dent. Res. v.92 Asmussen, E.
  10. Dent. Mat. v.11 Lee, S. Y.;Greener, E. H.;Menis, D. L.
  11. Dent. Mat. v.5 Kao, E. C.
  12. Anal. Chmica Acta v.346 del Olmo, M.;Gonzalez-Casado, A.;Navas, N. A.;Vilchez, J. L.
  13. J. Chromatigr. A v.883 Poskrobko, J.;Dejnega, M.;Kiedik, M.
  14. J. Chromatigr. A v.864 Pedersen, S. N.;Lindholst, C.
  15. Environ. Health Perspect. v.104 Olea, N.;Pulgar, R.;Perez, P.;Olea-Serrano, F.;Rivas, A.;Novillo-Fertrell, A.;Pedraza, V.;Soto, A. M.;Sonnenschein, C.
  16. Food and Drug Administration. FDA guidelines for chemistry and technology requirement of indirect additive petitions;
  17. J. Oral Rehab. v.25 Lee, S. Y.;Huang, H. M.;Lin, C. Y.;Shin, Y. H.
  18. J. Dent. Res. v.64 McKinney, J. E.;Wu, W.
  19. Dent. Mat. v.13 Hamid, A.;Hume, W. R.
  20. Eur. J. Oral Sci. v.107 Lygre, H.;Høl, P. J.;Solheim, E.;Moe, G.
  21. J. Biomed. Mater. Res. v.48 Vaubert, V. M.;Moon, P. C.;Love, B. J.
  22. J. Am. Dent. Assoc. v.128 Nathanson, D.;Lertpitayakun, P.;Lamkin, M. S.;Edalatpour, M.;Chou, L. L.
  23. J. Dent. Res. v.61 Wu, W.;McKinney, J. E.
  24. Dent. Mat. v.6 Ferracane, J. L.;Condon, J. R.
  25. J. Oral Rehabili. v.18 Tanaka, K.;Taira, M.;Shintani, H.;Wakasa, K.;Yamaki, M.

Cited by

  1. Elution study of unreacted Bis-GMA, TEGDMA, UDMA, and Bis-EMA from light-cured dental resins and resin composites using HPLC vol.b74, pp.1, 2005, https://doi.org/10.1002/jbm.b.30252
  2. Identification of organic extractables from commercial resin-modified glass-ionomers using HPLC-MS vol.8, pp.7, 2000, https://doi.org/10.1039/b604149c
  3. Effect of immersion in various media on the sorption, solubility, elution of unreacted monomers, and flexural properties of two model dental composite compositions vol.19, pp.6, 2000, https://doi.org/10.1007/s10856-008-3369-6
  4. HPLC ANALYSIS OF ELUTED MONOMERS FROM DENTAL COMPOSITE USING DIFFERENT IMMERSION MEDIA vol.37, pp.2, 2000, https://doi.org/10.1080/10826076.2012.738619