Low Temperature Processing of $SrBi_2Ta_2O_9$ Thin Films

  • Published : 2000.06.01

Abstract

$SrBi_2Ta_2O_9$ thin films were deposited at room temperature on the usual (111) oriented Pt bottom electrodes using r.f. magnetron sputtering, and then post-annealed at 650-$800^{\circ}C$ for 30min in oxygen flow. Low temperature processing which shows the preferred oriented SBT thin films was obtained by controlling the sputtering pressure and/or Sr content in target. The orientation and grain growth behavior of SBT thin films were dependent on Sr contents in films. With increasing the excess Bi content up to 50% in SBT thin films, it was possible to lower the onset temperature of grain growth. The c-axis preferred oriented SBT thin films were well-grown under the condition of low post-annealing($650^{\circ}C$) by lowering post-annealing pressure. After $10^{11}$ switching cycles, no polarization degradation was observed in both preferred oriented SBT capacitors.

Keywords

References

  1. Nature v.374 Fatigue-Free Ferroelectric Capacitors with Platinum Electrodes C.A-Paz de Araujo;J.D.Cuchiaro;L.D.McMillan;M.C.Scott;J.F.Scott
  2. J.Mater.Res. v.12 no.8 Structural Development Studies of SrBi₂(TaNb)₂O Thin Films T.C.Chen;T.Li;X.Zhang;S.B.Desu
  3. J.Mater.Res. v.12 The Effect of Excess Bismuth on the Ferroelectric Properties of SrBi₂Ta₂O Thin Films T.C.Chen;T.Li;X.Zhang;S.B.Desu
  4. Appl.Phys.Lett. v.69 Oriented Growth of SrBi₂Ta₂O Ferroelectric Thin Films S.B.Desu;D.P.Vijay;X.Zhang;B.He
  5. Appl.Phys.Lett. v.66 Preparation and Ferroelectric Properties of SrBi₂Ta₂O Thin Films K.Amanuma;T.Hase;Y.Miyasaka
  6. Jpn.J.Appl.Phys. v.34 Preparation of Bi-Based Ferroelectric Thin Films by Sol-Gel Method T.Atsuki;N.Soyama;T.Yonezawa;K.Ogi
  7. Jpn.J.Appl.Phys. v.35 Analysis of the Dependence of Ferroelectric Properties of Strontium Bismuth Tantalate (SBT)Thin Films on the Composition and Process Temperature T.Noguchi;T.Hase;Y.Miyasaka
  8. Jpn.J.Appl.Phys. v.35 Crystallization of Sr Bi Ta O Thin Films by Chemical Liquid Deposition I.Koiwa;T.Kanehara;J.Mita;T.Iwabuchi;T.Osaka;S.Ono;M.Maeda
  9. Jpn.J.Appl.Phys. v.36 Preparation and Dielectric Properties of SrBi₂Ta₂O Thin Films by Sol-Gel Method T.Hayashi;T.Hara;H.Takahashi
  10. Jpn.J.Appl.Phys. v.36 Role of Excess Bi in SrBi₂Ta₂O Thin Films Prepared Using Chemical Liquid Deposition and Sol-Gel Method I.Koiwa;Y.Okada;J.Mita;A.Hashimoto;Y.Sawada
  11. Appl.Phys.Lett. v.69 Structural and Ferroelectric Properties of the C-axis Oriented SrBi₂Ta₂O Thin Films Deposited by the Radio-Frequency Magnetron Sputtering T.K.Song;J.-K.Lee;H.J.Jung
  12. J.Voc.Sci.Technol A. Microstructure-Dependent Ferroelectric Properties in SrBi₂Ta₂O Thin Films Fabricated by the Radio Frequency Magnetron Sputtering K.J.Cho;Y.B.Park;S.H.Lee;H.J.Jung;J.K.Lee;J.W.Park
  13. J.Voc.Sci.Technol A. v.16 no.3 Microstructure-Dependent Ferroelectric Properties in SrBi₂Ta O Thin Films Fabricated by the Radio Frequency Magnetron Sputtering K.J.Cho;Y.B.Park;S.H.Lee;H.J.Jung;J.K.Lee;J.W.Park
  14. Intergrated Ferroelectrics v.21 Role of Abnormal Grain Growth on the Ferroelectric Properties of SrBi₂Ta₂Ta O Thin Films Fabricated by R.F.Magnetron Sputtering C.Bae;J.K.Lee;S.H.Lee;Y.B.Park;H.J.Jung
  15. J.Vac.Sci.TechnolA. v.17 no.5 Ex Situ Growth of the C-axis Preferred Oriented SrBi₂Ta₂O Thin Films on Pt/Ti/SiO₂/Si Substrates C.Bae;J.K.Lee;S.H.Lee;H.J.Jung
  16. Integrated Ferroelectrics v.14 Phase Formation and Characterization of the SrBi₂Ta₂O Layered-perovskite Ferroelectric M.A.Rodriguez;T.J.Boyle;C.D.Buchheit;R.G.Tissot;C.A.Drewien;B.A.Hernandez;M.O.Eatough