A Study on the Adsorption of Uranium(VI) Ion Using Ion Exchange Resin

이온 교환수지를 이용한 우라늄(VI) 이온의 흡착에 관한 연구

  • 강영식 (광주보건대학 환경위생과) ;
  • 김준태 (광주보건대학 환경위생과)
  • Published : 2000.12.01

Abstract

Several new ion exchange resins have been synthesized from chloromethyl styrene-1,4-divinylbenzine with 1%, 2%, 5% and 105-crosslink and macrocyclic ligands of cryptand type by interpolymerization method. The adsorption characteristics and the pH, time, solvents and concentration dependence of the adsorption of uranium ion by this resins were studied. The resins were very stable in both acidic and basic media and have good resistance to heat at $300^{\circ}C$. The uranium ion are not adsorbed on the resins below pH 3.0, but the power of adsorption of it increased rapidly above pH 4.0. The optimum equilibrium time for adsorption of uranium ion was two hours and adsorptive power decreased in proportion to crosslink size of the resins and order of dielectric constants of solvents used and the adsorption for uranium ion was bin the order of $OdienNtn-H_4$ > $OtnNen-H_4$ > $OtnNen-H_4$ > $OenNen-H_4$.

Keywords

References

  1. Nuclear chemistry and its Applications M. Haissinsky;D.G. Tuck(tr.)
  2. Solvent extraction on analytical chemistry G.H. Morrison;H. Freiser
  3. Talants v.18 M.M. Khater;J. Korisch
  4. J. Am. Chem. Soc. v.96 R.B. King;P.R. Heokly
  5. J. Am. Chem. Soc. v.99 R.M. Izatt;J.D. Lamb;J.J. christemen;B.L. Haymore
  6. J. Am. Chem. Soc. v.96 R.B. King;P.R. Heckly
  7. Anal. Chem. v.53 M. Igawa;K. Saito;J. Tsukamoto;M. Tanaka
  8. Talanta v.27 E. Blasius;K.P. Janzen;M. Keller;H. Lander;T. Nguyen Tien;G. Scholten
  9. Talanta v.27 E. Blasius;K.P. Janzen;W. Adrian;W. Klein;H. Klotz;H. Luxenburger;E. Mernke;V.B. Nguyen;T. Nguyen Tien;R. Rausch;J. Stockemer;A. Toussaint
  10. Makromol. Chem. v.178 E. Blasius;P.G. Maurer
  11. J. Chromater. v.167 E. Blasius;K.P. Janzen;H. Luxenburger;V. B. Nguyen;H. Klotz;J. Stockemer
  12. Inorg. Nucl. Chem. Lett. v.9 A. Cassol;A. Seinara;G. de Paoli
  13. Inorg, Nucl. Chem. Lett. v.12 R.M. Costes;G. Folcher;P. Plurien;P. Rigny
  14. Inorg. Nucl. Chem. Lett. v.13 J. Klimes;A. Knochel;G. Rudolph
  15. Inorg. Nucl. Chem. Lett. v.11 R. M. Cstes;G. Folcher;N. Keller;P. Plurien;P. Rigny
  16. Inorg. Chem. v.19 L.F. Lindoy
  17. Inorg. Chem. v.14 L.C. Amstrong;L.G. Lindoy
  18. U.S. Pat. v.3 L.D. Morse;W.T. Grundner;C. Calmon
  19. Eng. Chem. v.44 G.D. Jones, Indust
  20. Talanta v.27 E. Blausis;K.P. Janzen;M. Keller;H. Lander;T. Nguyen Tien;G. Scholten
  21. J. Adam. Chem. Soc. v.105 K.R. Adam
  22. J. Am. Chem. Soc. v.96 R.B. King;P.R. Heckley
  23. J. Am. Chem. Soc. v.93 H.k. Frensdorff
  24. J. Inorg. Nucl. Chem. v.40 G. Bombieri;G. de Paoli;A. Immizi
  25. Thesis for Degee of Ph. D., Korea Univ. M.Y. Suh
  26. Mikrochim. Acta E. Blasius;K.P. Janzen;W. Neumann