초록
Through an application of Micrometerorological methods, we conducted measurements of Hg fluxes from Nan-Ji-Do which is well known as one of the major local areal sources in Seoul metropolitan area during Match/April of 2000. In the course of our study, we determined the concentration gradients of total gaseous Hg(between 20 and 2000 cm heights) and combined these data with Micrometerorological components to derive is fluxes. It turned out that emission from and dry deposition to soil surfaces occurred at the ratio of 72:27 from a total of 271 hourly measurements. The validity of measured concentration gradients( or resulting fluxes) was evaluated in terms of percent gradient. Accordingly, about more than 95% of gradient data derived were statistically significant. The mean fluxes of Hg across soil-air interface, when computed using the concentrations gradients and relevant parameters, were found at 253(during emission) and -846ng/$m^2$/h(during dry deposition) The occurrences of abnormalously high exchange rates appear to be the combined effects of enormously high gradient values and high transfer coefficients. While the emissions of Hg occurred constantly during the whole study periods, the occurrences of dry deposition events were observed most intensively during very limited time periods(3/29 and 4/3). The results of our study cleary indicated that the studied area is a strong local areal source, while exhibiting great potential as a major sink simultaneously.
