한국재료학회지 (Korean Journal of Materials Research)

  • 제10권3호
  • /
  • Pages.233-240
  • /
  • 2000
  • /
  • 1225-0562(pISSN)
  • /
  • 2287-7258(eISSN)
한국재료학회 (Materials Research Society of Korea)
권호 표지

수용액 매체로부터 코디어라이트 졸의 제조 및 코디어라이트 세라믹스의 소결거동

Preparation of Cordierite sols in Aqueous Media and Sintering Behavior of Cordierite Ceramics

  • 김재원 (한국기계연구원 내열재료그룹) ;
  • 김현철 (한국기계연구원 내열재료그룹) ;
  • 김두현 (한국기계연구원 내열재료그룹) ;
  • 서성문 (한국기계연구원 내열재료그룹) ;
  • 조창용 (한국기계연구원 내열재료그룹) ;
  • 최승주 (한국기계연구원 내열재료그룹) ;
  • 김재철 (전력연구원 발전연구실)
  • 발행 : 2000.03.01
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초록

소결 촉진제 첨가없이 치밀한 코디어라이트 세라믹스를 얻기 위해 Mg-Al-Si계의 열적거동을 검토하였다. 수용액 매체에서 코디어라이트 현탁액의 분산안정성을 ESA를 이용하여 조사하였으며, 코디어라이트 졸의 응집 방지와 분산성을 부여하기 위해 2N $HNO_3$와 2N $NH_4OH$ 용액으로 pH 1.03과 pH 8.30로 조절하였다. pH 8.30인 코디어라이트 졸을 $150^{\circ}C$에서 12시간 건조한 시료에서 magnesium-aluminum-silicate 복합 겔이 존재하였다. 평형상태의 코디어라이트 겔의 결정화는 $1300^{\circ}C$ 이상의 소결 온도에서 존재하였으며, $1300^{\circ}C$ 이하의 조건에서는 ${\mu}-cordierite(Mg_2Al_4Si_5O_18)$, spine($MgAl_2O_4$) 및 mullite($Al_6Si_2O_{13}$)와 같은 다양한 준안정상이 복합적으로 혼재하였다. pH 1.03과 pH 8.30로 조절된 현탁액에서 코디어라이트 겔의 핵반응은 유사하게 일어났으나, 치말화거동은 졸의 pH에 상당한 차이를 보였다. pH 1.03인 졸 보다 pH 8.30인 졸의 치밀화가 더욱 진전되었다.

In order to fabricate dense cordierite ceramics without sintering aid, thermal behavior of Mg-Al-Si compounds during sintering was investigated. The dispersibility of cordierite suspension in aqueous media was measured by ESA(electrokinetic sonic amplitude). To prevent aggregation and insufficient dispersion of the cordierite sol, the pH of the suspension was controlled to 1.03 and 8.30 by adding $2N\;HNO_3$ and $2N\;NH_4OH$, respectively. Magnesium-aluminum-silicate complex gel coexisted in the specimen which has been gelled at $150^{\circ}C$ fir 12 hours, however several metastable phase such as ${\mu}-cordierite(Mg_2Al_4Si_5O_{18}),\;spine(MgAl_2O_4)\;and\;mullite(Al_6Si_2O_{13})$ existed below $1300^{\circ}C$ Nucleation rates of the two suspension were similar, but densification of the gel was sensitive to the pH of the sol. Densification of the sol with the pH of 8.3 was more pronounced than that of the sol with pH of 1.63.

키워드

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