대기 중 PM-10의 오염원 추정을 위한 다환방향족탄화수소와 무기원소자료의 예비통계분석 -1996년 2월~6월까지 대규모 영통건설지역 주변을 중심으로-

A Preliminary Statistical Stduy of Polycyclic Aromatic Hydrocarbons and Inorganic Elements Data for Extimation Ambient PM-10 Sources -Near the Huge Young-Tong Construction Area during Feb. 1996 to June 1996-

  • 손정화 (신흥기술연구소) ;
  • 황인조 (경희대학교 환경학과 및 환경연구소) ;
  • 김동술 (경희대학교 환경학과 및 환경연구소)
  • 발행 : 2000.02.01

초록

Polycyclic aromatic hydrocarbons(PAHs) have known as potentially hazardous air pollutants(HAPs0 to human health because of its carcinogenic and mutagenic behaviors. The purpose of this study was to determine the level of 6 PAHs(Fluoranthene, Pyrene, Benzo[a]anthracene, Chrysene, Benzo[b]fluoranthene, and Benzo[a]pyrene) as well as 10 inorganic elements(Cr, Na, K, Zn, Pb, Fe, Cu, Ti, Al and Cd) in the ambient PM-10. The total of 115 samples had been collected from February, 1996 to June, 1996 on quartz fiber by a PM-10 high volume air sampler near the Yong-Tong Apartment complexes. A statistical analysis was performed for the PAHs and inorganic elements data set using a principal component analysis in order to identify qualitatively the potential sources of PM-10. A total of 6 principal components were separated by intensive data pretrement and transformation processes, such as soil, refuse incineration, oil burning, coal burning, field burning, vehicle emission sources. The results showed that PAHs were associated with various burning activities like refuse and field burning, coal burning, and oil burning emissions in the study area. These derived sources were well matched with the previously known source profiles in terms of compositonal order and level of measured species. The combination data set consisted of both organic and inorganic species might provide more powerful source signature and might increase the number of potentially derived sources than PAHs or inorganic data alone.

키워드

참고문헌

  1. 다변량통계자료분석 김기영;전명식
  2. 유해대기오염물질의 규제 및 관리에 관한 조사연구 김동술
  3. 수원지역분진오염의 화학적 분석 및 발생원 조사 김동술
  4. 한국대기보건학회지 v.12 no.3 GC/FID를 이용한 PM-10 추출물 중의 다환방향족 탄화수소의 농도결정 김성천;이태정;김동술
  5. 수원통계연보 수원시
  6. 환경과학대학원 석사논문 다환방향족탄화수소(PAHs)의 실내외 농도 조사에 관한 연구 심규호
  7. 경희대학교 일반대학원 환경학과 박사학위논문 수원지역 입자상 오염물질 중 화학원소의 농도경향 및 기여도 추정에 관한 연구 이태정
  8. SPSS와 통계분석 허만형
  9. 한국대기보전학회지 v.14 no.1 Submicron 부유분진의 화학적 조성 및 분포에 관한 연구 황인조;김동술
  10. Chemosphere v.22 Phase distribution and particle size dependency of PAHs in the urban atmosphere Beak, S.O.;M.E. Goldstom;P.W.W Kirk;J.N. Lester;R. Perry
  11. Anal. Chem. v.65 Extraction of spiked versus native PAH from heterogencous environmental samples using supercritical fluid extraction and sonication in dich-loromethane Broddin, G.;W. Cautieels;K.A. Van Cauwenberghe
  12. Polynuclean Aromatic Hydrocarbons in the Amosphere in Biriningham Colwill, D.M.;J.D. Butler;P. Crossley
  13. Basic Concepts for Environmental Chemistry Connell, D.W.
  14. Journal of the Air & Waste Management Association v.39 no.1 Fate and effects of PAHs in the terrestrial environment-an overview Edwards, N T
  15. Environmental Science & Technoloy v.29 no.9 PAHs in air adjacent to two island water bodies Gardner, B.;N Hewitt;K C Jones
  16. Atmospheric Chemical Compound Sources, Occwrence, and Bioassay Graedel, T.E.;D.T. Hawkins;L.D. Claxton
  17. Receptor Modeling in Environmental Chemistry Hopke, P K
  18. Psychometrika v.23 no.3 The varimax criterion for analytic rotation in factor analysis Kaier, H F
  19. Atmospheric Environment v.29 no.4 PAH source fingerprints for coke ovens, diesel and gasoline engines, highway tunnels, and wood combustion emissions Khahli, N.R.;P.A. Scheft;T.M. Holsen
  20. Atmospheric Environment v.29 no.13 City centre concentiations of PAHs using supercritical fluid extraction Lewis, A.C.;Kupiszewska;K.D. Bartle;M.J. Pilling
  21. Environmental Science & Technology v.28 no.12 Effect of composition and state of organic components on polycyclic atomatic hydrocarbon decay in atmospheric aerosols McDow, S.R.;Q.R Sun;M. Valentiamen;Y.S. Hong;Y.L. Yao;T Fister;R.Q. Yao;R M Kamens
  22. Fundamentals of Organic Chemistry McMurry J
  23. Environmental Technology v.19 The relative proportions of polycyclic aromatic hydrocarbons and oxygenated derivatives in accumulated organic particulates as affected by air pollution sources Oda, J.;I. Maeda;T. Mori;A Yasuhara;Y. Saito
  24. Atmospheric Chemistry Pitte, F.B.J.;J.N Pitts
  25. Environmental Science & Technology v.29 no.8 Measurement of the particle-size distributions of semivolatile organic contaminants in the atmosphete Poster, D.L.
  26. Environmental Science & Technology v.25 no.6 Source of fine organic aerosol Ⅰ Charbroilers and meat-cooking operations Rogge, W F.;L.M. Hildemann;M A. Mazurek;G.R Cass;B.R.T. Simonett
  27. Atmospheric Environment v.30 no.23 Concentrations of particulate airborne polycyclic aromatic hydrocarbons and metals collected in Lahore Smith, D.J.T.;R M. Harrison;L Luhana;C.A. Pio;L.M. Castro;M.N. Tario;S. Hayat;T Quraishi
  28. Science of the Total Environment v.164 Effects of open-air burning of metal scrap on ambient PAHs concentrations Tsai, J.H.
  29. EPA-454/R-98-014 Locating and estimating air emissions from sources of polycyclic organic matter U.S. EPA
  30. Atmospheric Environment v.18 The gas-particle distribution of organic aerosol constituents: measurement of the volatilisation artifact in Hi-Vol cascade impactor sampling Van Vaeck, L.;K.A. Van Cauwenberghe
  31. Environmental Science & Technology v.28 no.4 Size distribution of polycyclic aromatic hydrocarbons and elemental carbon. 1. Sampling, measurement methods, and source characterization Venkataraman, C.;J.M Lyons;S.K. Friedlander
  32. Environmental Science & Technology v.25 no.2 Chemical and biological characterization of particulate-semivolatile-, and gas phase-associated compound in diluted heavy-duty diesel exhausts, a comparison of three different semivolatile-phase samplers Westerholm, R.;J Almen;H. Li;U. Rannug;K E Egcback;K Gragg