Korean Journal of Crystallography (한국결정학회지)

Korean Crystallographic Association (한국결정학회)
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$[Ni(dppe)_2]$의 합성 및 구조

Synthesis and Structure of $[Ni(dppe)_2] (dppe=Ph_2PCH_2CH_2PPh_2)$

  • Kim, Wan -Sung (Department of Chemistry, Sungkyunkwan University, Natural Science Campus, Suwon 440-746) ;
  • Lee, Ji-Hwa (Department of Chemistry, Sungkyunkwan University, Natural Science Campus, Suwon 440-746) ;
  • Lee, Soon W. (Department of Chemistry, Sungkyunkwan University, Natural Science Campus, Suwon 440-746)
  • Published : 2000.06.01
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Abstract

Compound [Ni(P(OEt)3)4] (1) reacted with bis(diphenylphosphino)ethane (Ph2PCH2CH2Ph2, dppe) to give bis(bis(diphenylphosphine)ethane)nickel(0), [Ni(dppe)2] (2). Compound 2 was characterized by spectroscopy (1H-and 31P{1H}-NMR) and X-ray crystallography. Crystallographic data for 2: monoclinic space group P21/n, a=9.826(1)Å, b=21.167(2)Å, c=21.425(2)Å, β=91.957(9)°, Z=4, R(wR2)=0.0377(0.0882).

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