$Al_2O_3+Y_2O_3를 첨가한 {\beta}-SiC-TiB_2$ 복합체의 특성

Properties of the $\beta-SiC-TiB_2$ Composites with $Al_2O_3+Y_2O_3$ additives

  • 임승혁 (성균관대 전기전자 및 컴퓨터학부) ;
  • 신용덕 (원광대 전기전자공학부) ;
  • 주진영 (원광대 전기전자공학부) ;
  • 윤세원 (원광대 전기전자공학부) ;
  • 송준태 (성균관대 전기전자 및 컴퓨터학부)
  • Yim, Seung-Hyuk (Dept.of Electric Electronics Computer Engineering, Sungkyunkwan University) ;
  • Shin, Yong-Deok (Dept.of Electric Electronics Engineering, Wonkwang University) ;
  • Ju, Jin-Young (Dept.of Electric Electronics Engineering, Wonkwang University) ;
  • Yoon, Se-Won (Dept.of Electric Electronics Engineering, Wonkwang University) ;
  • Song, Joon-Tae (Dept.of Electric Electronics Computer Engineering, Sungkyunkwan University)
  • 발행 : 2000.07.01

초록

The mechanical and electrical properties of pressed and annealed $\beta-SiC-TiB_2$ electroconductive ceramic composites were investigated as a function of the liquid forming additives of $Al_2O_3+Y_2O_3$. Phase analysis of composites by XRD revealed $\alpha$-SiC(6H), TiB2, and (Al5Y3O12). Reaction between Al2O3 and $Y_2O_3$ formed YAG but the relative density decreased with increasing $Al_2O_3+Y_2O_3$ contents. The Flexural strength showed the value of 458.9 MPa for composites added with 4 wt% $Al_2O_3+Y_2O_3$ additives at room temperatures. Owing to crack deflection and crack bridging, the fracture toughness showed 6.2, 6.0 and 6.6 MPa.m1/2 for composites added with 4, 8 and 12 wt% Al2O3+Y2O3 additives respectively at room temperature. The resistance temperature coefficient showed the value of $3.6\times10^{-3},\; 2.9\times10^{-3}\; and\; 3.0\times10^{-3} /^{\circ}C$$^{\circ}C$ for composite added with 4, 8 and 12 wt% $Al_2O_3+Y_2O_3$additives respectively at room temperature. The electrical resistivity of the composites was all positive temperature coefficient resistance(PTCR) in the temperature range of $25^{\circ}C\; to\; 700^{\circ}$.

키워드

참고문헌

  1. Mamoru Mitomo 'Microstructural Development During Gas-Pressure Sintering of ${\alpha}$-Silicon Nitride' J. Am. Ceram. Soc., 75[1], pp. 103-108, 1992
  2. Nitin P. Padture 'In Situ-Toughened Silicon Carbide' J. Am. Ceram. Soc., 77(2), pp. 519-23, 1994 https://doi.org/10.1111/j.1151-2916.1994.tb07024.x
  3. Mamoru Mitomo, Young-Wook Kim, Hideki Hirotsuru 'Fabrication of Silicon carbide nanocerarnics' J. Mater. Res., Vol. 11, No.7, Jul 1996
  4. William D. Callister 'Materials Science and Engineering an Introduction' Fourth Edition, pp. 513, John Wiley & Sons, Inc. , 1996
  5. 山根正之 'セラミシクス基礎講座 4' pp. 151, 內田老鶴圃, 1988
  6. A. G. Evans and T. R. Wilshaw 'Quasi-Static Solid Particle Demage in Brittle Solids-1. Observation Analysis and Implication' Acta Metallurgica. Vol. 24, pp. 939-956, 1976
  7. 'Philips Research Reports' Philips Res. Repts 13, 1-9, 1958
  8. Yong Deok Shin 'Electric Discharge Machining of Hot-Pressed SiC-ZrB2 Composites Ceramic' Trans. KIEE. Vol. 46, NO.7, pp. 1062-1067, 1997
  9. Tor Grande, Hakson Sommerset, Eirik Hagen, Kjell wiik and Mari - Ann Einarsrud, 'Effect of Weight Loss on Uquid-Phase-Sintered Silicon Carbide' J. Am Ceram. Soc., 80[4], pp. 1047-1052, 1997
  10. Patricia A. Hoffman 'Thermo Elastic Properties of Silicon Carbide-Titanium Diboride Particulate Composites' M. S Thesis, 1992
  11. Jurgen Rodel 'Interaction Between Crack Deflection and Crack Bridging' Journal of the European Ceramic Society, 10, pp. 143-150, 1992 https://doi.org/10.1016/0955-2219(92)90027-B