Analysis of the Phase Change Temperatures and the Latent Heat Characteristics of $H_2O$-NaCl Mixtures for the Cold thermal Energy Storage

냉축열을 위한 $H_2O$-NaCl 혼합물의 상변화 온도와 잠열 특성분석

In this study $H_2O$-NaCl mixture was selected as a cold thermal storage material and its phase change temperature($liquid{\Leftrightarrow}solid$) was controlled with the molar concentration of NaCl. Ion dipole interaction mechanism and the fusion and crystallization structure of $H_2O$-NaCl were visualized with the low and high concentration of NaCl in the heating and cooling processes. In this study, the original cause of the appearance of two steps phase change period in heating and cooing processes were found by the visualization of the ion dipole interaction mechanism of $H_2O$-NaCl, and the theoretical equation of the phase change temperature variation in the NaCl high molar concentration was rearranged.

[ $H_2O$ ]-NaCl혼합물을 냉축열재로 선택하였으며, 이 혼합물의 상변화온도를 몰농도 변화에 의하여 조절하였다. 그리고 고농도와 저농도의 NaCl과 $H_2O$가 ion-dipole interaction으로 결합하는 구조를 그림으로 가시화하고 가열, 냉각과정에서 $H_2O$-NaCl이 동결, 융해하는 현상을 도시하므로서 융해와 동결과정에서 상변화온도가 2단계로 나타나는 구조적 원인을 구명하였으며, NaCl의 농도변화에 따른 상변화온도를 이론적으로 분석하므로서 실험 및 이론분석 결과의 타당성을 증명할 수 있도록 하였다.