Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Application of a Membrane Desolvator to the Analysis of Organic Solvents in Inductively Coupled Plasma Atomic Emission Spectrometry

  • Published : 1999.09.20
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Abstract

A micro porous PTFE membrane desolvator (MMD) was built and evaluated for the on-line removal of organic solvents to facilitate the determination of trace metal contaminants in the solvents by ICP-AES. Three organic solvents, isopropyl alcohol (IPA), methanol, and dimethy sulfoxide (DMSO) were studied. The MMD reduced organic solvent concentration in the sample aerosol stream by 82% to 89%, as indicated by monitoring C(I) emission. Net signal intensity of Fe, Al, and Cu was increasing with higher organic solvent concentration, with the rate of increase being solvent dependent. The signal intensities for Mg and Pb followed the trend with the C(I) signal. Changing the sweep gas flow rate affected the optimum signal intensity. Wine samples were analyzed by the method of standard addition. The concentrations of B, Al, and Mg were determined with a relative precision of less than 2.3%.

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References

  1. J. Anal. Atom. Spectrom. v.11 Vanhaeeke, F.;van Holderbeke, M.;Moens, L.;Dams, R.
  2. J. Anal. Atom. Spectrom. v.13 Todoli, J.-L.;Mermet, J.-M.
  3. J. Anal. Atom. Spectrom. v.13 Allen, L. B.;Siitonen, P. H.;Thompson, H. C. Jr.
  4. J. Anal. Atom. Spectrom. v.9 Weir, D. G.J.;Blades, M. W.
  5. J. Anal. Atom. Spectrom. v.9 Weir, D. G. J.;Blades, M. W.
  6. J. Anal. Atom. Spectrom. v.11 Weir, D. G. J.;Blades, M. W.
  7. J. Anal. Atom. Spectrom. v.11 Weir, D. G. J.;Blades, M. W.
  8. Spectrochim. Acta, part B v.43B no.8 Gustavsson, A.
  9. Spectrochim. Acta part B v.44B no.10 Backstrom, K.;Gustavsson, A.;Hietala, P.
  10. Spectrochim Acta, part B v.45B no.9 McLaren, J. W.;Lam, J. W.
  11. Spectrochim. Acta, part B v.45B no.10 Gustavsson, A.;Hietala, P.
  12. J. Anal. Atom. Spectrom. v.13 Fitzgerald, N.;Tyson, J. F.;Leighty, D. A.
  13. Spectrochim. Acta, part B v.50B no.4-7 Sundin, N. G.;Tyson, J. F.;Hanna, C. P.;McIntosh, S. A.
  14. Spectrochim. Acta, part B v.51B Yang, J.;Conver, T. S.;Koropchak, J. A.
  15. J. Anal. Chem. v.355 Brenner, I. B.;Zhu, J.;Zander, A. Fresnius
  16. J. Anal. Atom. Spectrom. v.12 Brenner, I. B.;Zander, A.;Plantz, M.;Zhu, J.
  17. J. Anal. Atom. Spectrom. v.11 Botto, R. I.;Zhu, J.
  18. J. Anal. Atom. Spectrom. v.9 Botto, R. I.;Zhu, J.
  19. J. Anal. Atom. Spectrom. v.13 Minnich, M. G.;Houk, R. S.
  20. Anal. Atom. Spectrom. v.11 Augagneur, S.;Medina, B.;Szpunar, J.;Lobinski, R. J.
  21. Talanta v.45 Akinbo, O. T.;Carnahan, J. W.