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Tailoring of the Porosity in Sol-Gel Derived Silica Thin Layers


초록

The sol-gel process enables the preparation of ceramic thin films ranging in characteristics from dense to highly porous layers. Based on the example of silica layers, this paper focuses on the importance of the choice of the various synthesis parameters to tailor the porosity of the final material and new opportunities associated to the templating effect. The problems related to the characterization of the porosity in the case of thin films are also considered.

키워드

참고문헌

  1. Sol-gel science, the physics and chemistry of sol-gel processing Brinker, C. J.;Scherer, G. W.
  2. J. Am. Ceram. Soc. v.65 Frost, H. J.;Raj, R.
  3. Thesis, University of Nancy (France) Ben Aim, R.
  4. Proceedings of Journal sur la prearation, la caracterisation et la manipulation des poudres ceramiques, Paris (France) Troadec, J. P.;Bideau, D.
  5. Proceedings Ecole d'e Procedes sol-gel, Bombannes (France) v.Ⅱ Quinson, J. F.
  6. Science of Ceramic Chemical Processing Zarzycki, J.;Hench, L.L.(Ed.);Ulrich, D.R(Ed.)
  7. Thin Solid Films v.201 Brinker, C. J.;Frye, G. C.;Hurd, A. J.;Ashley C. S.
  8. J. of Materials Sc. Letters v.13 Ayral, A.;Guizard, C.;Cot, L.
  9. J. Sol-Gel Sci. and Technol. v.2 Nakanishi, K.;Yamasaki, Y.;Kaji, H.;Soga, N.;Inoue, T.;Nemoto, N.
  10. Nature v.359 Kresge, C. T.;Leonowicz, M. E.;Roth, W. J.;Vartuli, J. C.;Beck, J. S.
  11. J. Am. Chem. Soc. v.114 Beck, J. S.;Vartuli, J. C.;Roth, W. J.;Leonowicz, M. E.;Kresge, C. T.;Schmitt, K. D.;Chu, C. T. W.;Olson, D. H.;Sheppard, E. W.;McCullen, S. B.;Higgins, J. B.;Schenker, J. L.
  12. Langmuir v.13 Martin, J. E.;Anderson, M. T.;Odinek, J.;Newcomer, P.
  13. Microporous materials v.10 Anderson, M. T.;Martin, J. E.;Odinek, J.;Newcomer, P.;Wilcoxon, J. P.
  14. Thesis, University of Montpellier (France) Dabadie, T.
  15. Mat. Res. Soc. Symp. Proc. v.346 Dabadie, T.;Ayral, A.;Guizard, C.;Cot, L.;Robert, J. C.;Poncelet, O.
  16. J. Mat. Chem. v.6 Dabadie, T.;Ayral, A.;Guizard, C.;Cot, L.;Lacan, P.
  17. Proceedings of the Third International Conference on Inorganic Membranes, Worcester (USA) Dabadie, T.;Ayral, A.;Guizard, C.;Cot, L.;Robert, J. C.;Poncelet, O.;Ma, Y. H.(Ed.)
  18. Klotz, M.;Ayral, A.;Guizard, C.;Cot, L.
  19. Nature v.379 Yang, H.;Kuperman, A.;Coombs, N.;Mamiche-Afara, S.;Ozin, G. A.
  20. Nature v.381 Yang, H.;Coombs, N.;Sokolov, I.;Ozin, G. A.
  21. J. Mat. Chem. v.7 Yang, H.;Coombs, N.;Sokolov, I.;Ozin, G. A.
  22. Chem. Commun. Raimondi, M. E.;Maschmeyer, T.;Templer, R. H.;Seddon, J. M.
  23. Phys. Rev. Letters v.64 Fabre, P.;Casagrande, C.;Veyssie, M.;Cabuil, V.;Massart, R.
  24. Mat. Res. Soc. Symp. Proc. v.519 Klotz, M.;Ayral, A.;Van der Lee, A.;Guizard, C.;Menager, C.;Cabuil, V
  25. Powder surface area and porosity Lowell, S.;Shields, J. E.
  26. J. Mat. Res. Soc. Symp. Proc. v.121 Frye, G. C.;Ricco, A. J.;Martin, S. J.;Brinker, C.
  27. J. Non Cryst. Solids v.183 Fardad, M. A.;Yeatman, E. M.;Dawnay, E. J. C.;Green, M.;Horowitz, F.
  28. J. Mat. Sc. Letters v.17 Ayral, A.;El Mansouri, A.;Vieira, M. P.;Pilon, C.