Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Photoreaction of 1-(o-Acetoxyphenyl)-2-pentamethyldisilanyl Ethyne

  • Published : 1999.05.20
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Abstract

Irradiation of 1-(o-acetoxyphenyl)-2-pentamethyldisilanyl ethyne 2 in benzene yields the photo-Fries rearrangement products 5 and 6 and a photoproduct 4 via silacyclopropene intermediate.

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References

  1. J. Am. Chem. Soc. v.99 Ishikawa, M.;Fuchikami, Y.;Kumada, M.
  2. J. Organomet. Chem. v.194 Ishikawa, M.;Nishimura, K.;Sugisawa, H.;Kumada, M.
  3. Organometallics v.31 Seyferth, D.;Vick, S. C.;Shannon, M. L.
  4. J. Am. Chem. Soc. v.104 Ishikawa, M.;Sugisawa, H.;Fuchikami, Y.;Kumada, M.;Yamabe, T.;Kawakami, H.;Fukui, K.;Ueki, Y.;Shizuka, H.
  5. J. Phy. Chem. v.91 Shizuka, H.;Okazaki, K.;Tanaka, H.;Tanaka, M.;Ishikawa, M.;Sumitani, M.;Yoshihara, K.
  6. J. Org. Chem. v.59 Kwon, J. H.;Lee, S. T.;Hoshino, M.;Shim, S. C.
  7. J. Chem. Soc., Perkin Trans. v.2 Shim, S. C.;Lee, S. T.
  8. Bull. Korean Chem. Soc. v.16 no.10 Shim, S. C.;Lee, S. T.
  9. Organometallics v.15 Lee, S. T.;Baek, E. K.;Shim, S. C.
  10. Bull. Korean Chem. Soc. v.19 no.6 Shim, S. C.;Park, S. K.
  11. Tetrahedron Lett. Shim, S. C.;Park, S. K.
  12. J. Chem. Soc., Chem. Commun. Sakurai, H.;Yamagata, M.