Bulletin of the Korean Chemical Society

  • 제20권10호
  • /
  • Pages.1200-1204
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  • 1999
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Reaction of Ru(tpy)$Cl_3$ with N,N,C-Terdentates, 3,2'-Annulated-6-(2"-pyridyl)-2-phenylpyridines

  • 발행 : 1999.10.20
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초록

The reactions of Ru(tpy)Cl3 (tpy = 2,2';6',2"-terpyridine) with new N,N,C-terdentate ligands, 3,2'-annulated-6-(2"-pyridyl)-2-phenylpyridines (1, HL) and the properties of their Ru(II) complexes are described. The distribution ratio of the two possible Ru(II) complexes, a pentaaza-coordinated complex [Ru(tpy)(1-N,N')Cl]+ and a cycloruthenated complex [Ru(tpy)(La-N,N',C)]+ are highly dependent on the length of the polymethylene unit. The trimethylene bridge of the N,N,C-terdentate in pentaaza-coordinated complex is rigid enough to induce an asymmetry in the complex.

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참고문헌

  1. Photochemistry of Polypyridine and Porphyrin Complexes Kalyanasundaram, K.
  2. Inorg. Chim. Acta v.186 Collin, J.-P.;Beley, M.;Sauvage, J.-P.;Barigelletti, F.
  3. J. Chem. Soc. Chem. Comm. Constable, E. C.;Thompson, A. M. W. C.;Greulich, S.
  4. J. Am. Chem. Soc. v.102 Hegedus, L. S.;Allen, G.;Olsen, D.
  5. J. Org. Chem. v.43 Marahasi, S.-I.;Tamba, Y.;Yamamura, M.;Yoshimura, N.
  6. Metal-DNA Chemistry Suggs, J. W.;Higgins Ⅲ, J. D.;Wagner, R. W.;Millard, J. T.;Tullius, T. D.(ed.);ACS Symposium Series 402(ed.)
  7. J. Chem. Soc., Dalton Trans. Constable, E. C.;Henney, P. G.;Leese, T. A.;Tocher, D. A.
  8. Inorg. Chim. Acta v.211 Constable, E. C.;Hannon, M. J.
  9. Inorg. Chem. v.36 Jahng, Y.;Thummel, R. P.;Bott, S. C.
  10. Principles and Applications of Organotransition Metal Chemistry Collman, J. P.;Hegedus, L. S.
  11. J. Org. Chem. v.52 Jahng, Y.;Thummel, R. P.
  12. Inorg. Chim. Acta v.267 Park, J. G.;Jahng, Y.
  13. J. Org. Chem. v.61 Riesgo, E. C.;Jin, X.;Thummel, R. P.
  14. Aust. J. Chem. v.16 Dwyer, F. P.;Goodwin, H. A.;Gyarfas, F. C.
  15. Inorg. Chem. v.25 Thummel, R. P.;Jahng, Y.