M ssbauer Study and Atomic Migration in MgFe2O4

  • Lee, Seung Wha (Chungbuk National University) ;
  • Yoon, Sung Hyun (Kunsan National University) ;
  • An, Sung Yong (Kookmin University) ;
  • Kim, Woo Chul (Kookmin University) ;
  • Kim, Chul Sung (Kookmin University)
  • 발행 : 1999.12.01

초록

$MgFe_2O_4$ has been studied with X-ray diffraction, M ssbauer spectroscopy and vibration sample magnetometer (VSM). The crystal structure of the sample is found to have a cubic spinel structure with a lattice constant of $a_0=8.390$\pm$0.005$\AA$.$ The iron ions at both A (tetrahedral) and B (octahedral)sites are found to be in ferric high-spin states. Its Neel temperature TN is found to be 710$\pm$3 K. The Debye temperature for the A and B sites found to be 417$\pm$5 K and 331$\pm$5 K., respectively. Atomic migation from the A to the B sites starts near 425 K and increases rapidly with increasing temperature to such a degree that 31% of the ferric ions at the A sites have moved over to the B sites by 600 K.

키워드

참고문헌

  1. Phys. Rev. v.B19 C. M. Srivastava;G. Srinivasn;N. G. Nanaddikar
  2. Phys. Rev. v.187 G. A. Sawatzky;F. Van der Woude;A. H. Morrish
  3. Physica B v.96 G. De Grave;A. Govaert;D. Chambaere
  4. Phys. Rev. v.B36 H. N. Ok;Y. K. Kim
  5. Proc. Phys. Soc. v.57 J. B. Nelson;D. P. Riley
  6. J. Appl. Phys. v.79 C. S. Kim;Y. J. Lee;S. W. Lee;Y. B. Kim;C. S. Kim
  7. Phys. Rev. v.B40 H. N. Ok;K. S. Baek;E. J. Choi
  8. J. Appl. Phys. v.79 C. S. Kim;S. W. Lee;S. I. Park;J. Y. Park;Y. J. Oh
  9. J. Korean Phys. Soc. v.31 S. W. Lee;S. I. Park;S. B. Kim.;C. S. Kim;H. N. Ok
  10. Z. Phys. v.159 R. L. Mossbauer;W. H. Wiedermann
  11. J. Phys. Radium v.12 E. F. Bertaut