Textile Science and Engineering (한국섬유공학회지)

The Korean Fiber Society (한국섬유공학회)
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Durable Flame-Retardant Finish of PET/Cotton Blended Fabrics with Br and P Compounds

브롬 및 인 화합물을 이용한 PET/면 혼방직물의 내구성 방염가공

  • Published : 1999.11.01

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Abstract

PET/cotton (65/35, 50/50, 40/60) blended fabrics were treated with tetrabromobisphenol A (TBBA)-epichlorohydrin (EPI) by a pad-batch method and/or tetrakis (hydroxy methyl) phosphonium chloride (THPC)-urea by a pad-batch method in an 1 or 2-batch process. Flame retardancy and synergism between Br and P compound were investigated through the LOI measurements. Durability of flame retardant was tested by laundering and flame-retardant mechanisms are also discussed based on thermogravimetric analysis. When fabrics were treated with TBBA-EPI or THPC-urea, both system improved the flame retardancy of blended fabrics. Though THPC-urea was more effective of the two, sufficient self-extinguishing property could not be obtained. When fabrics were treated with two kinds of flame retardant in a 2-bath system, Br-P synergism was observed. Durability of flame retardant was proved by laundering test. The flame-retardant mechanism of TBBA-EPI was confirmed as gas phase mechanism and that of THPC-urea was confirmed as condensed phase mechanism by thermogravimetric analysis.

Keywords

References

  1. Text. Res. J. v.46 B. Miller;J. R. Martin;C. H. Meiser Jr.;M. Gargiullo
  2. J. Soc. Dyer. Color. v.105 A. R. Horrocks
  3. Flame Retardancy Polym. Mater. v.5 R. H. Barker;G. L. Drake Jr.;J. E. Hendrix;J. E. Bostic Jr.
  4. Text. Res. J. v.49 E. M. Pintauro;D. R. Buchanan
  5. J. Appl. Ploym. Sci. v.17 B. Miller;J. R. Martin;C. H. Meiser Jr.
  6. J. Appl. Polym. Sci. v.24 N. Inatagi;T. ShinTani;H. Kunisada;K. Katsuura
  7. Text. Res. J. v.51 J. V. Beninate;B. J. Trask;G. L. Drake Jr.
  8. J. Fire Retardancy Chem. v.4 no.59 R. J. Berni;M. M. Smith;R. R. Benento
  9. J. Fire Retardancy Chem. v.3 J. D. Timpa;L. B. Chance;W. R. Goynes Jr.
  10. 分析化學(日) v.14 本下盛雄(等)
  11. Anal. Chem. v.27 D. N. Bernhart;A. R. Wreath
  12. Am. Dyestuff Reporter v.63 W. F. McSherry;Georgy L. Draker Jr.;A. B. Cooper;A. R. Markezich
  13. Handbook of Fiber Science and Technology v.2 M. Lewin
  14. J. Macromolecular Sci. Chem. v.A21 Banjai;Chakrapani;Jha
  15. Flame Retardant Polymeric Materical v.2 C. W. Jarvis;R. H Barker
  16. J. Fire Flam. v.5 I. E. Pensa;S. B. Sello;W. Bernner