The Effect of Acrylic Acid Graft on the Hemoglobin Removing Rate of Nylon Fabric (I) -Surface and Structure Analysis of Grafted Nylon Fabric-

아크릴산으로 그라프트 중합한 나일론 직물의 혈액단백질 오구 세척성에 관한 연구(I) -그라프트 나일론 직물의 표면 및 구조분석-

  • 오수민 (숙명여자대학교 의류학과) ;
  • 송화순 (숙명여자대학교 의류학과)
  • Published : 1999.08.01

Abstract

The graft polymerization of acrylic acid (AA) onto nylon fabric was performed using ammonium persulfate (APS) as an initiator. The surface morphology and the structure change of the nylon fabric after graft polymerization were studied by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), and X-ray photoelectron spectroscopy (XPS). The properties of the AA-grafted nylon fabric, such as moisture regain, contact angle, and the hemoglobin removing rate were also investigated. The graft polymerization ratio increased with increasing AA concentration. The surface of grafted nylon became rougher with increasing graft ratio. FT-IR analysis confirmed the introduction of the COOH group. In the XPS spectra, intensities and areas of C 1s peak at 290 eV and O 1s peak at 531.6 eV increased due to grafting and Na 1s peak at 1070.99 eV was newly introduced by grafting and alkaline treatment. The moisture regain of the nylon fabric improved after alkaline treatment. The contact angle also decreased after grafting and alkaline treatment. Therefore, this result implies that the effect of graft on the hemoglobin removing rate is related with the changes in contact angle and moisture regain.

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References

  1. J. Korean Fiber Soc. v.33 W. S. Song
  2. J. Korean Fiber Soc. v.9 K. A. Kim;S. R. Kim
  3. J. Korean Fiber Soc. v.26 S. S. Shin;S. Y. Kim;S. K. Song
  4. Polymer International v.38 A. M. El-Naggar;K. El-Salmawi;S. M. Ibraheim;A. H. Zaharan
  5. J. Korean Fiber Soc. v.29 K. P. Lee;S. K. Song
  6. Journal of the Research Institute of Industrial Sciences(Hanyang Unversity) v.29 S. K. Song;K. P. Lee
  7. Handbook of Fiber Science and Technology v.Ⅱ E. Kissa;M. Lewin(ed.);S. B. Sello(ed.)
  8. Jpn. Res. Assn. Text. End-Uses v.25 Y. Tokoro;T. Fujii;M. Minagawa
  9. Text. Res. J. v.62 T. Kawase;M. Uchita;T. Fizii;M. Minagawa
  10. J. Korean Soc. of Clothing and Textiles v.12 H. W. Chung;S. R. Kim
  11. J. Korean Soc. of Clothing and Textiles v.20 J. S. Lee;S. R. Kim
  12. 大版市立大學家政學部紀要 v.20 皆川基
  13. Dyers Colour. v.85 G. J. Howard;S. T. Kim;R. H. Peters
  14. 特許公報 昭34-7248
  15. J. Korean Soc. of Clothing and Textiles v.19 C. E. Baik;S. S. Cho;W. S. Song
  16. Text. Res. J. v.61 T. Kawase;M. Uchita;T. Fizii;M. Minagawa
  17. 세제와 세탁의 과학 김성련