한국섬유공학회지 (Textile Science and Engineering)

  • 제36권7호
  • /
  • Pages.572-579
  • /
  • 1999
  • /
  • 1225-1089(pISSN)
  • /
  • 2288-6419(eISSN)
한국섬유공학회 (The Korean Fiber Society)
권호 표지

Diaminotetrachlorocyclotriphosphazene에 의한 DGEBA의 경화와 열적성질

Curing of an DGEBA by Diaminotetrachlorocyclotriphosphazene and Its Thermal Properties

  • 발행 : 1999.07.01

⟨ 이전 논문 다음 논문 ⟩

초록

Several derivatives of aminocyclotirphosphazene were prepared from hexachlorocyclotriphosphazene and used for the curing agent of diglycidyl ether bisphenol A(DGEBA). The effect of the curing agent on the dynamic viscoelastic properties. flame proofing, and heat resistance of the cured epoxy resins were investigated and compared with aliphatic and aromatic amines. The epoxy resin cured by 1,1-diamino-3,3,5,5-tetrachlorocyclotriphosphazene showed the highest storage modulus and glass transition temperature when cured at 19$0^{\circ}C$ for 4 hours. The expoxy resins cured with phosphazene derivatives showed superior flame proofing to those of alphatic amine and aromatic amines. Particularly 1,1-diamino-3,3,5,5-tetrachlorocyclotriphosphazene was an effective curing agent for epoxy resin to enhance the storage modulus, flame proofing, and resistance to heat.

키워드

참고문헌

  1. J. Polym. Sci. Part A: Polym. Chem. v.35 Y.-L. Lin
  2. J. Polym. Sci. v.35 S. R. Jong
  3. J. Appl. Polym. Sci. v.34 C.-P. Yang;T.-M. Lee
  4. J. Appl. Polym. Sci. v.39 W. Charmas; W. Podkoscielny
  5. Polymer Communications v.29 A. L. Mukundan;K. Balasubramanian;K. S. V. Srinivasan
  6. プラスチックス v.38 唐川安弘;喜多晉三
  7. 强化プラスチックス v.33 小也常夫
  8. J. Appl. Polym. Sci. v.39 Y. Nakamura;M. Yamaguchi;A. Kitayama;K. Iko
  9. J. Polym. Sci. v.35 J. H. Varley
  10. J. Materials Sci. London v.30 A. J. Kinloch
  11. J. Polym. Sci. v.35 M. Franco
  12. J. Appl. Polym. Sci. v.57 A. Padma
  13. J. Appl. Polym. Sci. v.56 M. F. Nograro
  14. J. Appl. Polym. Sci. v.55 G. Sanz
  15. ェポキシ樹脂 垣內弘
  16. 强化プラスチックス v.36 尹興洙;石川直元;高橋淸久
  17. J. Soc. Materials Sci. v.39 K. Takahashi;N. Ishikawa;H. S. Yoon
  18. Kobunshi Ronbunshu v.47 K. Takahashi;N. Ishikawa;H. S. Yoon
  19. Kobunshi Ronbunshu v.47 K. Takahashi;N. Ishikawa;T. Komori;H. S. Yoon
  20. J. Korean Fiber Soc. v.27 H. S. Yoon;Y. M. Won;S. I. Mah;K. Takahashi;N. Ishikawa;M.Kajiwara
  21. 경북산업대학 논문집 v.6 윤흥수
  22. J. Soc. Materials Sci. v.37 K. Takahashi;T. Yamamoto;M. Kajiwara
  23. J. Korean Fiber Soc. v.28 H. S. Yoon;S. I. Mah;Y. M. Won;M. W. Huh;K.Takahashi;M. Kajiwara
  24. J. Soc. Materials Sci. v.40 K. Takahashi;N. Ishikawa;T. Kohno;H.S. Yoon
  25. J. Korean Fiber Soc. v.33 H. S. Yoon;K.S. Choi;K. Takahashi
  26. J. Chem. Sci., (A), Inorg, Phys. Theor. M. V. Lenton;B. Lewis
  27. J. Inorg. Nucl. Chem. v.29 G. R. Feistel;T. Moeller
  28. Inorg. Chem. v.5 E. T. McBee;K. Okuhara;C. J. Moton
  29. J. Chem. Soc. R. Keat;R. A. Shaw
  30. Polyhedron v.2 M. Kajiwara; Y. Kurachi
  31. 工化 v.72 稻恒,;勝浦
  32. Textile Res.J. v.45 K. Katsuura and N, Inagaki