Spectrophotometric Study of Carminic Acid and Its Aluminum Complex in Aqueous Solution

카르민산과 그 알루미늄 착물의 분광학적 고찰

  • 이범훈 (한양대학교 공과대학 섬유공학과) ;
  • 정용식 (한양대학교 공과대학 섬유공학과) ;
  • 이근환 (국립기술품질원 섬유과) ;
  • 김진우 (한양대학교 공과대학 섬유공학과)
  • Published : 1999.02.01

Abstract

Properties of carminic acid, a colorant extracted from the dried female Coccid insect, and its aluminum complexes in aqueous solution were determined by spectrophotometric methods. Carboxyl and hydroxyl groups in carminic acid show acidic characteristics. The three apparent dissociation constants $(K_{a})$ of carminic acid were determined and the absorption spectra for the different dissociation species were demonstrated. Aluminum could form 1:1 and 2:1 complex with carminic acid in aqueous solution. Apparent formation constants $(K_{f})$ for the formation of each of the complexes were determined.

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