Transcrystallinity in iPP/cellulose allomorphs and PBS/cellulose allomorphs

iPP/cellulose allomorph와 PBS/cellulose allomorph에서의 Transcrystallinity 현상

  • Published : 1999.01.01

Abstract

Transcrystalline phenomenon was investigated in iPP/cellulose and PBS/cellulose systems. Cellulose allomorphs were prepared and the morphology was investgated at the interface of iPP/cellulose allomorphs and PBS/cellulose allomorphs by optical micrography. The cellulose fiber which had crystalline structure of cellulose II showed nucleating ability to iPP matrix. This observation is different from other works that no transcrystallinity was induced on Fortisan, other regenerated cellulose fiber and mecerized cellulose fiber. Cellulose allomorphs, also, showed nucleating ability to iPP and PBS. Nucleating ability of cellulose I, $III_{I}$, or $IV_{I}$ was higher than that of cellulose II, $III_{II}$, or $IV_{II}$. With increase in the isothermal crystallization temperature, nucleating ability of cellulose and growth rate of transcrystalline layer were decreased.

Keywords

References

  1. Polymer Science and Technology v.33 M. B. Amin;A. J. Maasdhah;A. M. Usmani;E. Carraher, Jr.(ed.);L. H. Spherling(ed.)
  2. J. Appl. Polym. Sci. v.61 J. R. Collier;M. Lu;M. Fahrurrozi;B. J. Collier
  3. Additives in Plastics P. Hamed;A. Y. Coran;R. B. Seymour(ed.)
  4. Copolymer, Polyblends and Composites N. G. Gaylord;N. Platzer(ed.)
  5. Comp. Sci. Tech. v.56 C. Joly;R. Gauthier;B. Chabert
  6. Polym. Comp. v.18 S. S. Im;T. J. Kim;Y. M. Lee
  7. J. Appl. Polym. Sci. v.56 A. Teisher;G. Maron
  8. J. Mater. Sci. v.29 J. M. Felix;P. Gatenholm
  9. 26th Annual Technical Conference on Reinforced Plastics E. Bear;J. L. Koening;J. B. Lando;M. Litt
  10. Kolloidz v.129 E. Jenckel;E. Teega;W. Flinkicks
  11. J. Apply. Polym. Sci. v.50 D. T. Quilline;D. F. Gaulfied;J. A. Koutsky
  12. Ind. Eng. Chem. v.44 D. Turnbull;B. Vonegut
  13. J. Polym. Sci. Polym. Phys. v.18 D. Campbell;M. M. Qayyum
  14. Polym. Eng. Sci. v.32 no.4 E. J. H. Chen;B. Hsiao
  15. J. Polym. Sci. v.8 D. R. Fitchmum;S. Newman
  16. Macromol. Chem. v.181 L. Goldfard
  17. J. Polym. Sci. Polym. Phys. Ed. v.13 A. M. Chatterjee;F. P. Price;S. Newman
  18. J. Polym. Sci.; Polym. Phys. C. Wang;L. M. Hwang
  19. J. Polym. Sci., Polym. Lett. Ed. v.12 D. G. Gray
  20. Introduction to Polymer Crystallization A. Sharples
  21. Cellulosic Polymers, Blends and Composites D. Gilbert
  22. J. Mater. Sci. v.10 T. Bessell;J. B. Shortall
  23. Mat. Res. Soc. Symp. Droc.,170 Interface in Composites B. S. Hsiao;E. J. H. Chen;C. G. Pantano(ed.);E. J. H. Chen(ed.)
  24. J. Polym. Sci. Polym. Phys. Ed. v.13 A. M. Chatterjee;F. P. Price;S. Newman
  25. Polymer v.11 F. L. Binsbergen;B. G. M. De Lange
  26. Macromolecules v.28 S. S. Im;E. S. Yoo;K. J. Ihn