Synthesis of Amide from Thioamide by Treatment of SiO2 or SeO2

  • Jung, Dai-Il (Corresponding author, Department of Chemistry, Dong-A University, Pusan 604-714) ;
  • Lee, Jin-A (Department of Chemistry, Dong-A University, Pusan 604-714) ;
  • Lee, Do-Hun (Um-Gung Middle School, San 3-1, Um-gung Dong, Sa-sang Gu, Pusan 617-030) ;
  • Kwak, Moon-Jung (Um-Gung Middle School, San 3-1, Um-gung Dong, Sa-sang Gu, Pusan 617-030) ;
  • Lee, Soo-Jin (Um-Gung Middle School, San 3-1, Um-gung Dong, Sa-sang Gu, Pusan 617-030) ;
  • Park, You-Mi (Um-Gung Middle School, San 3-1, Um-gung Dong, Sa-sang Gu, Pusan 617-030) ;
  • Park, Soon-Kyu (Um-Gung Middle School, San 3-1, Um-gung Dong, Sa-sang Gu, Pusan 617-030) ;
  • Kim, Hyun-Sook (Um-Gung Middle School, San 3-1, Um-gung Dong, Sa-sang Gu, Pusan 617-030)
  • 발행 : 1999.10.01

초록

Reactions of 2,6-Lutidine with active methyl group anilines in the presence of sulfur gave the desired thioamides 1. Reactions of synthesized thioamides 1 with sulfur and SiO2 or SeO2 gave the corresponding amide 2. We now report conversion of thioamide to amide by using oxidzing inorganic reagant

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