Journal of Photoscience

Korean Society of Photoscience (한국광과학회)
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THE DISSOCIATION RATE OF $^1O_2(^1Δg)$ DIMOL IN SOLUTION PHASE

  • Chou, Pi-Tai (Department of Chemistry , The National Chung-Cheng Univeristy) ;
  • Chen, Youn-Chan (Department of Chemistry , The National Chung-Cheng Univeristy)
  • Published : 1999.05.01
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Abstract

The ratio of dissociation rate $textsc{k}$-acversus the radiative decay rate $textsc{k}$D of the 1O2(1Δg) dimol has been determined to be $1.5\times$109 by its relaxation dynamcis in combination with a two-step O2((1Δg) sensitizing tetratert-butylphthalocoyanine luminescence. Consequently, with a known $textsc{k}$D value of 1.2 $\times$103S-1 , 10$textsc{k}$-ac has been extracted to be 1.8 $\times$1012S-1 CDCl3.

Keywords

References

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