Journal of Photoscience

Korean Society of Photoscience (한국광과학회)
권호 표지

Recent Developments in Radiationless Transitions

  • Hayashi, M. (Institute of Atomic and Molecular Science , Academic Sinica Taipei) ;
  • Liang, K.K. (Institute of Atomic and Molecular Science , Academic Sinica Taipei) ;
  • Chang, C.H. (Institute of Atomic and Molecular Science , Academic Sinica Taipei) ;
  • Mebel, A. (Institute of Atomic and Molecular Science , Academic Sinica Taipei) ;
  • Lin, S.H. (Institute of Atomic and Molecular Science , Academic Sinica Taipei)
  • Published : 1999.05.01
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Abstract

In this paper, the historicla development of radiationless transitions will be briefly reviewed. The paper will then focus on the ab inition calculations of internal conversion rate constants with emphasis on the case of small polyatomic molecules where the Duschinsky effect is important . As an example, we have chosen the new expressions for singlevibronic level rate constants of radiationless transitions. This type of rate constants is important in femto-second processes.

Keywords

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