Bulletin of the Korean Chemical Society

  • 제19권6호
  • /
  • Pages.686-689
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  • 1998
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  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Photoreaction of 1-(o-Allyloxyphenyl)-2-pentamethyldisilanylethyne with Methanol or Acetone

  • 발행 : 1998.06.20
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초록

Irradiation of 1-(o-allyloxyphenyl)-2-pentamethyldisilanylethyne (2) in methanol yields two 1 : 1 photoaddition products (3 and 4) via silacyclopropene intermediate. Photolysis of (2) with acetone in deaerated methylene chloride yields site specific and regioselective 1: 1 adducts (7 and 8) via silacyclopropene and 1-sila-1,2-propadiene intermediate, respectively.

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참고문헌

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