Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Reaction Phosphite with Acetal Derivatives:Syntheses of 1-Alkoxymethylphosphonates and 1-Alkylthiomethylphosphonates

  • Published : 1998.02.20
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Abstract

1-Alkoxymethylphosphonates 4 and 1-alkylthiomethylphosphonates 5 can be prepared by the reaction of actal derivatives and diethyl trimethylsilyl phosphite in the presence of Lewis acid under mild conditions. The dependency of the chemoselectivities with Lewis acid on the reaction of O,S-acetals with phosphites is described.

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References

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