Corrosion of Quartz Crystal Marine Sensors in Sea Water

항만센서용 수정진동자의 해수에 의한 부식

  • 최광재 (동아대학교 화학공학과) ;
  • 장상목 (동아대학교 화학공학과) ;
  • 김영한 (동아대학교 화학공학과)
  • Published : 1998.12.01

Abstract

A quartz crystal analyzer is utilized to monitor the corrosion process of an aluminum surface of a quartz crystal for marine sensor by sea water. A quartz crystal having 2000 $\AA$ of aluminum layer is installed in a specially designed cell and is in contact with sea water imitated electrolyte solution. While a constant potential is applied to the cell, the resonant frequency and resonant resistance are simultaneously measured using the quartz crystal analyzer. In addition, surface topographs are taken with an atomic force microscope(AFM) and the element analysis of the surface is conducted using an energy dispersive X-ray spectrometer(EDX). The simultaneous measurement of resonant frequency and resonant resistance during the corrosion process explains the change of surface structure caused by the corrosion. The variation of resonant frequency addresses the amount surface metal dissolution. As a conclusion, it is found that a simple measurement using the quartz crystal analyzer can replace the complex monitoring employing large equipments in the investigation of a corrosion process of sensor surface.

Keywords

References

  1. Surf. Interf. Anal. v.25 Multi-method Analysis of the Metal/Electrolyte Interface: Scanning Force Microscopy (SFM), Quartz Microbalance Measurements (QMB), Fourier Transfrom Infrared Sprctroscopy (FTIR) and Grazing Incidence X-ray Diffractometry (GIXD) at a Polycrystalline Copper Electrode W. Kautek;M. Gauss;M. Sahre;P. Zaho;S. Mirwald
  2. Anal. Chem. v.64 Quartz Crystal Detector for Microrheological Study and Its Application to Phase Transition Phenomena of Langmuir-Blodgett Films H. Muramatsu;K. Kimura
  3. Electrochem. Sci. Tech. v.128 Cathodic Behavior of Impure Aluminum in Aqueous Media K. Nisancioglu;K. Y. Davanger;O. Strandmyr
  4. Tech. Rep. Electrochemical Behavior and Surface Chemistry of Aluminum Alloys: Solute-Rich Interphase Model G. D. Davis;B. A. Shaw;B. J. Ress;E. L. Principe;C. A. Pecile;A. S. Iyengar
  5. Anal. Chem. v.60 Computation of Equivalent Circuit Parameters of Quartz Crystals in Contact with Liquids and Study of Liquid Properties H. Muramatsu;E. Tamiya;I. Karube
  6. J. Electroanal. Chem. v.347 Micro-Rheology Changes of Nafion Films with Electrochemical Mass-Transport in Hydroquinone Solutions and in situ Measurement Using a Quarz Crystal Analyzer H. Muramatsu;X. Ye;T. Ataka
  7. J. Electrochem. Soc. v.136 Pitting of Sputtered Aluminum Alloy Thin Films G. S. Frankel;M. A. Russak;C.V. Jahnes;M. Mirzamaani;V. A. Brusic