On the Properties and Synthesis of Nanostructured W-Cu alloys by Mechanical Alloying(II) Sintering Behavior of MA NS W-Cu Composite Powders

기계적 합금화 방법으로 제조된 nanostructured W-Cu 합금의 제조 및 물성 연구(II) -MA NS W-Cu 복합분말의 소결거동-

  • 김진천 (한양대학교 재료공학과)
  • Published : 1998.06.01

Abstract

Sintering behavior of nanostructured(NS) W-Cu powders prepared by mechanical alloying (MA) was investigated as a function of sintering temperature. MA NS W-2owt%Cu and W-3owt%Cu composite powders with the crystal size of 20-30 nm were annealed at 90$0^{\circ}C$, and thermal characteristics of those powders were investigated by DSC. Sintering behavior of MA NS W-Cu composite powders was investigated during the solid-state sintering and the Cu-liquid phase sintering. The new nanosintering phenonenon of MA W-Cu powders at solid-state sintering temperature was suggested to explain the W-grain growth in the inside of MA powders. The sintering densification of MA NS W-Cu powders was enhanced at Cu melting temperature by arrangement of MA powders, i.e., the first rearrangement of MA powders was occurred, and then the rearrangement of W-grains in the sintered parts was also took place during liquid-phase sintering, i.e., the second rearrangement was happened. Due to the double rearrangement process of MA NS W-Cu powders, the high sintered density with more than 96%o was obtained and the fine and high homogeneous state of W and Cu phases was achieved by sintering at 1200 $^{\circ}C$.

Keywords

References

  1. Intern. J. Powder Metall. v.30 R.M. German;K.F. Hens;J.L. Johnson
  2. Journal of Metals no.7 C. Zweben
  3. Proceedings of 1st Japan-Korea Workshop on Powder Injection Molding I. H. Moon
  4. Interb. J. Powder Metall. & Powder tech. v.17 K. V. Sebastian
  5. Powder Metall. Intcrn v.19 J. Lezanski;W. Rutkowski
  6. NanoStructured Materials v.6 J. S. Lee;T. H. Kim
  7. Metallwerk Plansee, Reutte v.1 Proceedings of the 13 International Plansee Seminar Q. Chongliang;W. Enxi;E. Zhiqiang;Z. Yuhua;H. Bildstein(ed.);R. Eck(ed.)
  8. Advanced in Powder metallurgy & Particulate materials-1996 I. H. Moon;S. H. Kim;J. C. Kim
  9. Mat. Sci. Eng. v.134A E. Gaffet;C. Louison;M. Harmelin;F. Faudot
  10. 한국재료학회지 v.4 인태형;이석운;주승기
  11. 한국분말야금학회지 v.4 김진천;류성수;이 혁;문인형
  12. NanoStructured Materiala v.6 T. Abound;B.-Z. Weiss;R. Chaim
  13. Metallurgical Transactions v.5 J. S. Benjamin;T. E. Volin
  14. Powder metallurgy International v.9 I. H. Moon;J. S. Lee
  15. Powder metallurgy v.22 I. H. Moon;J. S. Lee
  16. Elements of Materials Science and Engineering(6th ed.) L. H. Van Vlack
  17. The Principles of Engineering Materials C. R. Barrett;W. D. Nix;A. S. Tetelman
  18. Differential Thermal Analysis, M. I. Pope;M. D. Judd
  19. Scripta Metallurgicaet Materialia v.25 R. J. Dowding;K. J. Tauer
  20. NanoStructured Materials v.5 C.-S. Xiong;Y.-H Xiong;H. Zhu;T.-F. Sun;E. Dong;G.-X Liu
  21. 대한금속학회지 v.31 이 성;홍문희;김은표;송흥섭;노준웅;김영우
  22. Publish in Nanostructured materials J. C. Kim;I. H. Moon
  23. Acta Metallurgica et Materilia v.43 O. Drbohlav;A. R. Yavari
  24. NanoStructured materials v.4 M. I. Alymov;E. I. Maltina;Y.N. Stepanov
  25. MPIF and APMI v.15 Modern Developments in Powder metallurgy, J. S. Lee;W. A. Kaysser;G. Petzow;E. N. Aqua(ed.);C. I. Whitman(ed.)
  26. Acta metallurgica v.23 W. J. Huppmann;H. Rigger