Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Complex Chalcogenides as Thermoelectric Materials: A Solid State Chemistry Approach

  • Published : 1998.12.20
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Abstract

A solid state chemical approach to discover new mateials with enhanced thermoelectric properties is described. The aim is to construct three-dimensional bismuth chalcogenide framework structures which contain tonically interacting alkali or alkaline earth atoms. The alkali atoms tend to have soft "rattling" type phonon modes which result in very low thermal conductivity in these materials. Another desirable feature in this class of compounds is the low crystal symmetry and narrow band-gaps. Several promising materials such as BaBiTe3, KBi6.33S10, K2Bi8S13, β-K2Bi8Se13, K2.5Bi8.5Se14, Ba4Bi6Se13, Eu2Pb2Bi6Se13, Al1+xPb4-2xSb7+xSe15 (A=K, Rb), and CsBi4Te6 are described.

Keywords

References

  1. CRC Handbook of Thermolelectrics Rowe, D.M.(ed.)
  2. Introduction to Solid State Physics(6th eds.) Kittel, C.
  3. Thermoelectric Demiconductors Encyclopedia of Materials Sciences and Engineering
  4. Mat, Res. Soc. Symp. Proc. Thermoelectric Materials-New Ditections and Apprtoaches Tritt, T.M.;Kanatzidis, M.G.;Lyon, H.B.;Mahan, G.D.(ed.)
  5. ONR Quartely Review;ⅩⅩⅦ Thermoelectric Materials:Solid State Synthesis Kanatzidis, M.G.;DiSalvo, F.J.
  6. Mater. Res. Bull. v.23 Electron Crystals and Phonon Glasses:A New Path to Improved Thermoelectric Materials Sales, B.C.
  7. Science v.272 Filled Skutterudite Antimonides:A New Class of Thermoelectric Materials Sales, B.C.;Mandrus, D.;Williams, R.K.
  8. Phys. Rev. B. v.56 Filled Skutterdite Antinomides:Electron Crystals and Phonon Glasses Sales, B.C.;Mandrus, D.;Chakoumakos, B.C.;Keppens, B.;Thompson, J.R.
  9. J. Phys. Chem. Solids v.59 Thermoelectric Properties of the Semiconducting Chevrel Phase $Mo_2Re_4Se_8$ Caillat, T.;Fleurial, J.P.
  10. J. Phys. B. v.10 Study of Chevrel Phases for Thermoelectric Applications: Band Structure Calculations on $MxMo_6Se_8$ compounds(M=metal) Roche, C.;Pecheur, P.;Toussaint, G.;Jenny, A.;Scherrer, H.;Scherrer, S.
  11. Science v.272 Thermoelectric Run Hot and Cold Tritt, T.M.
  12. Chem. Mater. v.10 Synthesis of Metastable Post-Transition-Metal Iron Antimony Skutterudites using the Multilayer Precursor Method Sellinschegg, H.;Stuckmeyer, S.L.;Hornbostel, M.D.;Johnson, C.D.
  13. Appl. Phys. Lett. v.72 Effect of Ti Substitution on the Thermoelectric Properties of the Pentatelluride Materials %M_{1-x}Ti_xTe_5$ (M=Hf, Zr) Littleton, R.T.;Tritt, T.M.;Feger, C.R.;Kolis, J.;Wilson, M.L.;Marone, M.;Payne, J.;Verebeli, D.;Levy, F.
  14. J. Alloy Comp. v.268 An X-ray Study of the Mixed-Layered Compounds of $(GeTe)_n(Sb_2Te_3)_m$ Homologous Series Karpinsky, O.G.;Shelimova, L.E.;Kretova, M.A.
  15. Inorg. Mater. v.34 Structure Study of Ternary Layered Compounds in the $(GeTe)_n(Sb_2Te_3)_m$ and $(GeTe)_n(Sb_2Te_3)_m$ Honologous Series Karpinsky, O.G.;Shelimova, L.E.;Kretova, M.A.
  16. J. Alloy Comp. v.265 X-ray Study of the $(GeTe)_n(Sb_2Te_3)_m$ Mixed Layered Trtradymite-like Compounds Karpinsky, O.G.;Shelimova, L.E.;Kretova, M.A.
  17. J. Phys. Chem. Solids v.58 Preparation and Thermoelectric Properties of Semiconducting $Zn_4Sb_3$ Caillat, T.;Fleurial, J.P.;Borshchevskv, A.
  18. Mat. Res. Soc. Symp. Proc. v.478 Searching for New Thermoelectrics in Chemically and Structurally Complex Bismuth Chalcogenides in Thermoelectric Materials-New Directions and Approaches Chung, D.Y.;Hogan, T.;Schindler, J.;Iordanidis, L.;Brazis, P.;Kannewurf, C.R.;Chen, B.;Uher, C.;Kanatzidis, M.G.;Tritt, T.M.(ed.);Kanatzidis, M.G.(ed.);Lyon, H.B.(ed.);Mahan, G.D.(ed.)
  19. Prog. Inorg. Chem. v.43 The Application of Polychalcogenide Salts to the Exploratory Synthesis of Solid State Multinary Chalcogenides at Intermediate Temperatures Kanarzidis, M.G.;Sutorik, A.
  20. Curr. Opin. Solid St. Mater. v.2 Novel thermoelectric materials Sales, B.C.
  21. Appl. Phys. Lett. v.73 Semiconducting Ge Clathrates : Promising Candidates for Thermoelectric Applications Nolas, G.S.;Cohn, J.L.;Slack, G.A.;Schujman, S.B.
  22. J. Appl. Phys. v.79 The Effect of Rare-Earth Filling on the Lattice Thermal Condictivity if Skutterudites Nolas, G.S.;Slack, G.A.;Morelli, D.T.;Tritt, T.M.;Ehrlich, A.C.
  23. J. Amer. Chem. Soc. v.109 A New Low-Temperature Route to Metal Polychalcogenides-Solid-State Synthesis of $K_4TI_2S_{14}$ A Novel One-Dimensional compound Sunshine, S.A.;Kang, D.;Ibers, J.A.
  24. Chem. Ber. v.130 Layered Ternary and Quaternary Metal Chalcogenides Pell, M.A.;Ibers, J.A.
  25. Chem. Ber. v.129 Crystal Structures and Preparation of $K_2AgVS_4 and Rb_2AgVS_4$ by using the Molten Flux Method: Low-Dimensional Materials with Infinite Metal-Ion-Centered Tetrahedra Chains Bensch, W.;Durichen, P.
  26. New Materials and Perfoemance Limits for Thermoelectric Cooling in CRC Handbook of Thermoelectrics Slack, G.A.;Rowe, D.M.(ed.)
  27. in Solid State Physics v.34 Slack, G.A.;Eurenreich, H.(ed.);Seitz, F.(ed.);Turnbull, D.(ed.)
  28. J. Amer. Chem. Soc. v.119e Oligomerization Versus Polymerization of $Te_x^{2-}$ in the Polytelluride Compound $BaBiTe_{3-}$ Structural Characterization, Electronic Structure and Thermoelectric Properties Chung, D.Y.;Jobic, S.;Hogan, T.;Kannewurf, C.R.;Brec, R.;Rouxel, J.;Kanatzidis, M.G.
  29. Mat. Res. Soc. Symp. Proc. v.453 Thermoelectric Properties and Electronic Structure of $BaBiTe_3$ in Solid State Chemistry of Inorganic Materials Chung, D.Y.;Jobic, S.;Hogan, T.;Kannewurf, C.R.;Brec, R.;Rouxel, J.;Kanatzidis, M.G.;Davis, P.K.(ed.);Jacobson, A.J.(Ed.);Torardi, C.C.(ed.);Vanderah, T.A.(ed.)
  30. Chem. Mater. v.8 Synthesis and Thermoelectric Properties of the New Ternary Bismuth Sulfides $Kbi_{6.33}S_{10} and K_2Bi_8S_{13}$ Kanatzidis, M.G.;Macathy, T.J.;Tanzer, T.A.;Chen, L.H.;Iordanidis, L.;Hogan, T.;Kannewurf, C.R.;Uher, C.;Chen. B.
  31. Z. Kristallogr. v.140 A Redetermination of the Crystal Structure of Cosalite, Pb_2Bi_2S_5$ Srikrishnan, T.;Nowacki, W.Z.
  32. Chem. Mater. v.9 Transport Properties of $Bi_2S_3$ and the Ternary Bismuth Sulfides $K_2Bi_8S_{13} and Kbi_{6.33}S_{10}$ Chen. B.;Uher, C.;Iordanidis, L.;Kanatzidis, M.G.
  33. work in progress Brown, S.;Chung, D.Y.;Kanatzidis, M.G.
  34. Chem. Mater. v.9 High Thermopower and Low Thermal Comductivity in Semiconducting Ternary K-Bi-Se Compounds. Synthesos and Properties of ${\beta}-K_2Bi_8Se_{13) and K_{2.5}Bi_{8.5}Se_{14}$ and their Sb Analogs Chung, D.Y.;Choi, K.Y.;Iordanidis, L.;Schindler, J.K.;Brazis, P.W.;Kannewurf, C.R.;Chen, B.;Hu, S.;Uher, C.;Kanatzidis, M.G.
  35. Proc. Inter. Conf. Thermoelect.(7th) Complex Bismuth Chalcogenides as Thermoelectrics Chung, D.Y.;Hogan, T.;Schindler, J.L.;Iordianidis, L.;Brazis, P.W.;Kannewurf, C.R.;Chen, B.;Uher, C.;Kanatzidis, M.G.
  36. Mat. Res. Soc. Symp. Proc. v.478 Electrical Properties and Figures of Merit for New Chalcogenide-Vased Thermoelectric Materials in Thermoelectic Materials-New Directions and Approaches Schindler, J.L.;Hogan, T.P.;Brazis, P.W.;Kannewurf, C.R.;Chung, D.Y.;Kanatzidis, M.G.;Tritt, T.M.(ed.);Kanatzidis(ed.);Lyon, H.B.(ed.);Mahan, G.D.(ed.)
  37. Inorg. Chem. v.36 KthSb_2Se_6 and BaLaBi_2Q_6(Q=S, Se) Adopt a New Structure Type Stabilized with Dichalcogenide Groups Choi, K.S.;Iordanidis, L.;Chondroudis, K.;Kanatzidis, M.G.
  38. J. Solid State Chem. $ALn_{1{\pm}x}Bi_{4{\pm}x}S_8$ (A=K, Rb;Ln=La, Ce, Pr, Nd): New Semiconducting Quaternary Bismuth Sulfides Irodanidis, L.;Schindler, J.L.;Kannewurf, C.R.;Janatzidis, M.F.