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X-Ray Absorption Spectroscopy: A Complementary Tool for Structural and Electronic Characterization of Solids


Abstract

The purpose of this paper is to show that X-ray absorption spectroscopy (XANES and EXAFS) is a powerful technique for characterizing both crystalline and amorphous solids from structural (local order) and electronic point of view. The principle of this technique is briefly described by showing the main factors which must be considered for recording and fitting the experimental results. Some non-trivial examples have been selected for demonstrating that XAS spectroscopy is the only technique for bringing a definitive answer as for example: the determination of the local distortion of the $NiO_6$ octahedra in the $Li_{1-z}Ni_{1+z}O_2$ layered oxides and the evidence of the presence of copper pairs in the NASICON-type phosphate $CuZr_2 (PO_4)_3$. Are also reported some significant examples for which XAS spectroscopy is decisive with other characterization methods as (i) Raman spectroscopy for glasses (ii) Mossbauer spectroscopy for $LiNi_{1+z-t}Fe_To_2$ oxides (iii) magnetic measurements for Ce-based intermetallic compounds.

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References

  1. Synchrotron Radiation Research;Winich, H.;Doniach, S.(Eds.)
  2. Techniques and Application EXAFS SpectroscopyTeo, B.K.(Ed.);Joy, D.C.(Ed.)
  3. X-ray Absorption Principle, Applications, Techniques of EXAFS, SEXAFS and XANES Koningsberger, D.C.(Ed.);Prins, R.(Ed.)
  4. Springer Serise in Chemical Physics v.27 EXAFS and Near Edge Structure Bianconi, A.(Ed.);Incoccia, L.(Ed.);Stiprich(Ed.)
  5. Phys. Rev. Lett. v.27 Sayers, D.E.;Stern, E.A.;Lytel, F.W.
  6. Phys. Rev. v.B45 Greaves, G. N.;Dent, A. J.;Dobson, B. R.;Kalbitzer, S.;Pissini, S.;Muller, G.
  7. J. Am. Chem. Soc. v.99 Teo, B. K.;Lee, P. A.;Simons, A. L.;Eisenberg, P.;Kindkai, B. M.
  8. J. Phys. Paris Colloq. v.48 no.C9 Petrau, J.;Calas, G.;Sainctavit, P.
  9. Proceedings of the International Conference on X-ray and Inner-shell Process Petrau, J.;Calas, G.;Sainctavit, P.
  10. J. Phys. Condens. Matt. v.5 Kuzmin, A.;Purans, J.
  11. Phys. Rev. v.B47 Kuzmin, A.;Purans, J.;Benfatto, M.;Natoli, C. R.
  12. Phil Mag. v.B70 Kuzmin, A.;Grisenti, R.
  13. J. Phys. Condens. Matt. v.2 Prouzet, E.
  14. Phys. Rev. Lett. v.69 Rehr, J. J.;Albers, R. C.;Zabinski, S. I.
  15. Jpn. J. Appl. Phys. v.32 Rehr, J. J.
  16. Mat. Res. Bull. v.20 Thomas, M. G. S. R.;David, W. I. F.;Goodenough, J. B.
  17. J. Power Sources v.43;44 Broussely, M.;Perton, F.;Labat, J.;Staniewiez, R. J.;Romero, A.
  18. J. Electrochem. Soc. v.140 Ohzuku, T.;Iwakoshi, Y.;Sawai, K.
  19. J. Power Sources v.54 Broussely, M.;Perton, F.;Biensan, Ph.;Bodet, J. M.;Labat. J.;Lecerf, A.;Delmas, C.;Rougier, A.;Peres, J. P.
  20. Mat. Res. Bull. v.25 Morales, J.;Peres-Vicente, C.;Tirado, J. L.
  21. J. Electrochem. Soc. v.143 Rougier, A.;Gravereau, P.;Delmas, C.
  22. J. Phys. Chem. Solids v.5 Goodenough, J. B.;Wickham, D. G.;Croft, W. J.
  23. Solid State Ionics v.62 Li, W.;Reimers, J. N.;Dahn, J. R.
  24. J. Phys. Chem. Solids v.57 Peres, J. P.;Delmas, C.;Rougier, A.;Broussely, M.;Perton, F.;Biensan, P.;Willmann, W.
  25. These Universite Bordeaux 1 v.N° Rougier, A.
  26. Solid State Comm. v.94 Rougier, A.;Delmas, C.;Chadwick, A. V.
  27. These Universite Bordeaux 1 N° Peres, J. P.
  28. Solid State Ionics Peres, J. P.;Demourgues, A.;Delmas, C.
  29. Solid State Ionics v.90 Rougier, A.;Saadoune, I.;Gravereau, P.;Willmann, P.;Delmas, C.
  30. Takeda, Y.;Imanishi, N.;Nakahara, K.;Yamamoto, P.;Takano, M.
  31. Solid State Ionics v.61 Reimers, J. N.;Rossen, F.;Jones, C. D.;Dahn, J. R.
  32. J. Mat. Chem. v.2 Bush, T. S.;Richard, C.;Catlow, A.;Chadwick, A. V.;Cole, M.;Geatches, R. M.;Greaves, G. N.;Tomlison, S. M.
  33. Principles and Applications of Ferroelectrics and Related materials Lines, M. E.;Glass, A. M.
  34. Current Topics in Materials Science v.1 Rauber, A.;Kaldis, E.(Ed.)
  35. Opt. Eng. v.21 Pepper, D.M.
  36. Ferroelectrics v.13 Keune, W.;Date, S. K.;Gonser, U.;Bunzel, H.
  37. Phys. Rep. v.93 Gunter, P.
  38. J. Phys. Chem. Solids v.3 Schirmer, O. F.;Thiemann, O.;Wohleck, M.
  39. J. Chem. Phys. Phys. -Chim. Biol. v.85 Serghini, A.;Kacimi, M.;Zyiad, M.;Brochu, R.
  40. C. R. Acad. Sc. Ser. Ⅱ v.306 Le Polles, G.;Parent, C.;Olazcuaga, R.;Le Flem, G.;Hagenmuller, P.
  41. J. Phys. Condens. Matter v.4 Boutinaud, P.;Parent, C.;Le Flem, G.;Pedrini, C.;Moine, B.
  42. Acta Cryst. v.C48 Bussereau, I.;Belkhira, M. S.;Gravereau, P.;Boireau, A.;Soubeyroux, J. L.;Olazcuaga, R.;Le Flem, G.
  43. Inorg. Chem. v.24 Rath, N. P.;Holt, E.;Tanimura, K.
  44. Inorg. Chem. v.17 Mehotra, P. K.;Hoffmann, R.
  45. J. Phys. Chem. Solids v.9 Boutinaud, P.;Garcia, A.;Parent, C.;Faucher, M.;Le Flem, G.
  46. Eur. J. Solid State Inorg. Chem. v.29 Fargin, E.;Bussereau, I.;Le Flem, G.;Olazcuaga, R.;Cartier, C.;Dexpert, H.
  47. J. Solid State Chem. v.112 Fargin, E.;Bussereau, I.;Olazcuaga, R.;Le Flem, G.;Cartier, C.;Dexpert, H.
  48. Mat. Res. Bull. v.22 McCarron, E. M.;Calabrese, J. C.;Subramanian, M. B.
  49. Optical Materials v.4 Parent, C.;Boutinaud, P.;Le Flem, G.;Moine, B.;Prdrini, C.;Garcia, D.;Faucher, M.
  50. Glass Science and Technology v.48 Greaves, G. N.
  51. Application of Synchrotron Radiation Gurman, S. J.;Catlow, C. R. A.(Ed.);Greaves, G. N.(Ed.)
  52. Phys. Chem. Glasses v.32 Vogel, E. M.;Weber, M, J.;Krol, D. M.
  53. Phys. Rev. v.B43 Lines, M. E.
  54. J. Solid State Chem. v.120 Cardinal, T.;Fargin, E.;Flem, G. LE;Couzi, M.
  55. Nucl. Intr. and. Meth. In Phys. Res. v.B97 Cardinal, T.;Fargin, E.;Le Luyer, Y.;Le Flem, G.;Canioni, L.;Segonds, P.;Sarger, L.;Adamietz, F.;Ducasse, A.
  56. J. Phys. C.: Solid State Phys. v.21 Kugel, G. E.;Brehat, F.;Wyncke, B.;Fontana, M. D.;Marnier, G.;Caratabos-Nedelec, C.;Mangin, J.
  57. Comprehensive Inorganic Chemistry v.3 Bailar, J. C.;Hemeleus, H. J.;Nyholm, R.;Wong, J.;Trotman-Dickenson, A. F.;Bailar, J. C.(et al.)(Eds.)
  58. J. Solid State Chem. v.10 Blasse, G.; Van Den Hvevel, G. P. M.
  59. J. Non-Cryst. Solids v.45 Bertoluzza, A.;Marinangelli, A.;Morelli, M. A.;Simon, R.
  60. Eur. J. Solid State J-norg. Chem. v.31 Cardinal, T.;Fargin, E.;Le Flem, G.;Canioni, L.;Segonds, P.;Sarger, L.;Adamietz, F.;Ducasse, A.
  61. J. Solid State Chem. v.126 Berthereau, A.;Fargin, E.;Villesuzanne, A.;Olazcuaga, R.;Le Flem, G.;Ducasse, L.
  62. Proceedings, International Conference of Science and Technology of New Glasses Nasu, H.;Uchigaki, T.;Nakamura, M.;Kamiya, K.
  63. J. Non-Cryst. Solids v.110 Nasu, H.;Ibara, Y.;Kubodera, K.
  64. Mat. Res. Bull. v.29 Berthereau, A.;Le Luyer, Y.;Olazxuaga, R.;Le Flem, G.;Couzi, M.;Canioni, L.;Segonds, P.;Sarger, L.;Ducasse, A.
  65. J. Non-Cryst. v.168 Sekiya, T.;Mochida, N.;Ohtsuka, A.;Tonokawa, M.
  66. J. Solid State Comm. v.59 Buffat, B.;Chevalier, B.;Tuilier, M. H.;Lloret, B.;Etourneau
  67. Rev. Chim. Min. v.22 Wang-Xian-Zhong;Lloret, B.;Lam Ng, Wee;Chevalier, B.;Etourneau, J.;Hagenmuller, P.
  68. Phys. Rev. v.B28 Braun, H. F.;Engel, N.;Parthe, E.
  69. Acad. Sc. v.236 Lejay, P.;Higashi, I.;Chevalier, B.;Hirjak, M.;Etourneau, J.;Hagenmuller, P.
  70. Mat. Res. Bull. v.19 Hirjak, M.;Chevalier, B.;Etourneau, J.;Hagenmller, P.
  71. J. Nuclear Instruments and Methods in Physics Res. v.B97 Demourgues, A.;Chevalier, B.;Fourgeot, F.;Darriet, J.;Etourneau
  72. Phys. Rev. v.B26 Herbst, J. F.;Wilkins, J. W.
  73. Phys. Rev. Lett. v.35 Sales, B. C.;Wohlleben, D. K.
  74. J. Am. Chem. Soc. v.118 Arrio, M. A.;Sainctavit, Ph;Cartier, C.;Moulin, dit;Mallah, T.;Verdaguer, M.;Pellegrin, E.;Chen, C. T.
  75. J. Chem. Soc., Dalton Trans. v.609 Cartier, C.;Moulin, dit.;Momenteau, M.;Dartyge, E.;Fontane, A.;Tourillon, G.;Michalowicz, A.;Verdaguer, M.
  76. Catal. Lett. v.20 Clausen, B. S.;Graback, K.;Steffensen, G.;Hansen, P. L.;Topsoe, H.
  77. Nucl. Instr. and Meth. v.B97 Als Nielsen, J.;Grubel, G.;Clausen, B. S.
  78. Proceedings 1st European Conf. on Synchrotron Radiation in Materials Science Als Nielsen, J.;Grubel, G.;Clausen, B.S.
  79. Nucl. Instr. and Math. v.B97 Thomas, J. M.;Greaves, G. N.;Catlow, C. R. A.
  80. Catal. Lett. v.20 Thomas, J. M.;Greaves, G. N.
  81. Catal. Lett. v.20 Clausen, B.S.;Grabaer, L.;Steffensen, G.;Hansen, P. L.;Topsoe, H.
  82. Nucl. Intr. And Meth. v.B124 Landron, C.;Launay, X.;Riffet, J. C.;Etchegut, P.;Auger, Y.;Ruffer, D.;Coutrures, J. P.;Lemonier, M.;Gailhanou, M.;Bessiere, M.;Bazin, M.;Dexpert, H.
  83. Phys. Rev. Lett. v.63 no.4 Itie, J. P.;Polian, A.;Calas, A.;Petiau, J.;Fontaine, A.;Tolentino, H.
  84. Loubeyre, P.;Le Toullec, R.;Haneland, M.;Hausermann, D.