YAKHAK HOEJI (약학회지)

The Pharmaceutical Society of Korea (대한약학회)
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Synthesis of 4-Deoxyrhodomycinone Derivatives

4-데옥시로도마이시논 유도체의 합성

  • No, Yeong-Soe (Department of Chemistry, Chonbuk National University) ;
  • Kim, Sun-Ja (Department of Chemistry, Chonbuk National University) ;
  • Jo, In-Ho (Department of Chemistry, Chonbuk National University)
  • 노영쇠 (전북대학교 자연과학대학 화학과) ;
  • 김선자 (전북대학교 자연과학대학 화학과) ;
  • 조인호 (전북대학교 자연과학대학 화학과)
  • Published : 1997.02.01
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Abstract

A regiospecific total synthesis on the precursor(18b) of rhodomycinones is described. The anion of 3-carbomethoxy-1(3H)-isobenzofuranone(13) was respectively condensed wi th naphthalenone (12) and butenoate(8) derivatives which were, prepared by two different synthetic routes to afford 9-ethyl-6,7-dihydroxy 7,8,9,10-tetrahydronaphthacene-5,12 dione(18b) after oxidation and reduction.

Keywords

References

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