유기금속 착물 촉매에 의한 실란의 탈수소중합 반응

Dehydropolymerization of Silanes to Polysilanes Catalyzed by Organometallic Complexes

  • 우희권 (전남대학교 자연과학대학 화학과) ;
  • 송선정 (전남대학교 자연과학대학 화학과)
  • Woo, Hee Gweon (Department of Chemistry, College of Natural Science, Chonnam National University) ;
  • Song, Sun Jung (Department of Chemistry, College of Natural Science, Chonnam National University)
  • 발행 : 19970900

초록

실란탈수소중합 반응을 위한 촉매들 및 중합반응 메카니즘들을 정리하여 기술하였다. 치환기 재분배 및 실란 소중합체를 생성하는 후기 전이금속 착물 촉매들과는 달리 전기 전이금속 착물 촉매들 특히 4족 전이금속 메탈로센계 촉매의 효과가 우수하였다. 4족 전이금속 메탈로센계 촉매의 효과를 극대화 하기위한 노력들을 소개하였으며, 또한 다양한 치환기를 갖는 실란고분자의 합성, 실란고분자 유도체의 합성, 탈수소중합 촉매의 세라믹 화학에의 응용예들을 기술 하였다. 마지막으로 실란의 탈수소중합법의 미래 전망을 살펴 보았다.

This review deals with (1) the catalytic systems and mechanisms for the dehydropolymerization of silanes to polysilanes, (2) the dehydropolymerization of versatile silanes, (3) the preparation of polysilane derivatives, and (4) the applications of catalytic dehydropolymerizing systems to ceramics. The efforts to maximize the catalytic efficiency of group 4 metallocenes were introduced. Finally, the future of this dehydropolymerizing techniques of silanes was foreseen.

키워드

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