DOI QR코드

DOI QR Code

Complexation and Conformational Flexibility of Calix[4]arence Dibenzocrown Ethers

  • Published : 1997.09.20

Abstract

1,3-Dipropyloxycalix[4]arene dibenzocrown ethers were synthesized in the fixed 1,3-alternate conformation by the reaction of 1,3-dipropyloxycalix[4]arenes with a dibenzo dimesylates. Complexation toward alkali metal ions using ISEs showed a high cesium selectivity. Conformational flexibility of the corresponding 1,3-alternate calixcrown ether (4) with respect to the NMR time scale is found to depend on the temperature and polarity of the NMR solvent.

Keywords

References

  1. Calixarenes Gutsche, C. D.
  2. J. Am. Chem. Soc. v.113 Nijenhuis, W. F.;Buitenhuis, E. G.;de Jong, F.;Sudhoter, J. R.;Reinhoudt, D. N.
  3. J. Am. Chem. Soc. v.112 Ghizoli, E.;Harkema, S.;Abu El-Fald, A.;Reinhoudt, D. N.
  4. J. Incl. Phenom. Mol. Rec. Chem. v.13 Asfari, Z.;Abidi, R.;Arnaud, F.;Vicens, J.
  5. J. Am. Chem. Soc. v.117 Casnati, A.;Pochini, A.;Ungaro, R.;Ugozzoli, F.;Arnaud, F.;Fanni, S.;Schwing, M.-J.;Egberink, R. J. M.;de jong, F.;Reinhoudt, D. N.
  6. Anal. Chem. v.67 Asfari, Z.;Bressot, C.;Vicents, J.;Hill, C.;Dozol, J-F.;Rouquette, H.;Eymard, S.;Lamare, V.;Toumois, B.
  7. Bull. Korean Chem. Soc. v.18 Kim, J. S.;Cho, M. H.;Yu, I. Y.;Pang, J. H.;Kim, E. T.;Suh, I. H.;Oh, M. R.;Ra, D. Y.;Cho, N. S.
  8. Microchem. J. v.55 Kim, J. S.;Cho, M. H.;Lee, S. C.;Lee, Y.-I.;Sim, W.;Cho, N. S.
  9. Bull. Korean Chem. Soc. v.17 Kim, J. S.;Ohki, A.;Cho, N. S.;Yu, I. Y.;Hayashita, T.;Maeda, S.
  10. J. Korean Chem. Soc. v.40 Kim, J. S.;Ohki, A.;Cho, M. H.;Yu, I. Y.;Lee, S. C.;Lee, Y.-I.;Lee, J. H.;Cho, N. S.
  11. Pure Appl. Chem. v.67 Recommendation for Nomenclature of Ion-Selective Electrode
  12. Supramol. Chem. v.6 Bartsch, R. A.;Kim, J. S.;Olsher, U.;Purkiss, D. M.
  13. Solvents and Solvent Effects in Organic Chemistry(2nd Ed.) Reichart, C.
  14. Chem. Lett. Araki, K.;Shinkai, S.;Matsuda, T.