Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Optimization of Benzene Synthesis for Radicarbon Dating by Response Surface Method

  • Published : 1997.07.20
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Abstract

Response surface method was applied to the predicting optimum conditions of benzene synthesis for radiocarbon dating. The weight of carbon dioxide, the temperature of lithium container for producing acetylene and the activation temperature of catalyst which was used for the cyclization of acetylene to benzene were used as experimental factors. The yields of benzene synthesis were measured from twelve experiments which were carried out under various experimental conditions. The polynomial equation was obtained by using three experimental factors and yields. The validity of polynomial equation was confirmed by comparing the calculated yields with the experimental ones.

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References

  1. Science v.120 Suess, H. E.
  2. Nature v.172 Barker, H.
  3. Nature v.221 Barker, H.
  4. Radiocarbon v.33 Mestres, J. S.;Garcia, J. F.;Rauret, G.
  5. Int. J. Appl. Radiat. Isotopes v.29 Belluomini, G.;Delfino, A.;Manfra, L.;Petrone, V.
  6. Proc. 8th Int. Conf. Radiocarbon Dating v.1 Coleman, D. D.;Liu, C. L.;Dickerson D. R.;Frost, R. R.
  7. Proc. 6th Int. Conf. Radiocarbon and Tritium Dating Noakes, J. E.;Kim, S. M.;Stipp, J. J.
  8. Int. J. Appl. Radiat. Isotopes v.26 Tamers, M. A.
  9. Chemometrics: a textbook Massart, D. L.;Vandeginste, B. G. M.;Deming, S. N.;Michotte, Y.;Kaufman, L.
  10. J. Kor. Chem. Soc. v.36 Kim, S.;Lee, C.;Choi, S. W.;Kang, H. T.
  11. Anal. Sci. v.7 Shin, Y. K.;Kim, S.;Lee, C.
  12. J. Chromatogr. Sci. v.32 Li, K.;Ong, C. P.;Li, S. F. Y.
  13. J. High Res. Chromatogr. v.14 Ong, C. P.;Chin, K. P.;Lee, H. K.;Li, S. F. Y.
  14. Proc. 8th Int. Conf. Radiocarbon Dating v.1 Harkness, D. D.;Wilson, H. W.
  15. Proc. 8th Int. Conf. Radiocarbon Dating v.1 Polach, H.;Gower, J.;Fraser, I.
  16. Radiocarbon v.29 Polash, H. A.
  17. Radiocarbon v.25 Panarello, H. O.;Albero, M. C.;Angiolini, F. E.