Journal of Environmental Science International (한국환경과학회지)

The Korean Environmental Sciences Society (한국환경과학회)
권호 표지

Multi-Pesticide Residue Method for Organopesticide Analysis

유기농약 분석을 위한 Multi-Pesticide Residue Method

  • 김우성 (부산지방 식품의약품청) ;
  • 이봉헌 (부산지방 식품의약품청, 부산대학교 화학과, 인제대학교 환경학과)
  • Published : 1997.08.01
Download PDF
⟨ Previous Next ⟩

Abstract

Pesticide residues were extracted with 70% acetone and transferred to dichloromethane. Extracts were applied to open-column chromatography with florisil and alumina-N. The final extract was analyzed by gas chromatography with electron-capture detector(GC /ECD) and nitrogen-phosphorus detector(GC/NPD). Recoveries of the 17 organochlorine pegticides were ranged from 60.8 to 84.9% and those of 15 organophosphate pesticides, from 70.5% to 100.0%(except phosmet and azlnphos-methyls. The minimum detectable levels of this analytical method were low(0.021-0.058mg/kg).

농약 잔류물을 70% acetone으로 추출한 다음 dichloromethane 층으로 옮겨 추출물을 florisil과 alumina-N으로 충진시켜 column chromatography를 행하였다. 마지막 추출물을 electron-capture detector(GC/ECD)와 nitrogen-phosphorus detector(GC/NPD)를 가진 GC로 분석하였다. 분석 결과 17 가지의 유기염소계 농약과 15 가지의 유기인계 농약의 회수율이 각각 60.8 에서 84.9%와 70.5에서 100.0%의 범위이었으며(phosmet와 azlnphos-methyl은 제외) 본 분석 방법의 최소 검출 준위도 낮았다(0.021-0.058mg/kg).

Keywords

References

  1. Persistant Pesticides in the Environment Edwards, C. A.
  2. Modern Practice of Gas Chromatography(2nd ed.) Grob, R. L.
  3. The Chemistry of Pesticides Hassall, K. A.
  4. Analytical Gas Chromatography Jennings, W.
  5. Multi-residue pesticides screens, California Department of Food and Agriculture, Division of Inspection Services, Chemistry Laboratory Services Branch, Pesticide Residue Program Joe, T.
  6. J. Korean Envi. Sci. Soc. v.5 no.5 Kim, W. S.;Lee, B. H.;H. J. Park
  7. J. Korean Envi. Sci. Soc. v.6 no.2 Lee, B. H.;Kim, W. S.;Park, W. W.;Jeong, S. W.;H. J. Park
  8. Open Tubular Gas Chromatography, Theory and Practice Lee, M. L.;Yang, F.;K. Bartle
  9. J. Assoc. of Anal. Chem. v.98 Luke, M. A.;Froberg, J. E.;M. T. Masumoto
  10. Previous J. Anal. Chem. v.339 Mark, S.;Lee(et al.)
  11. J. Assoc. of Anal. Chem. v.46 Mills, P. A.;Onley, J. M.;R. A. Gaither
  12. Ecological Effects of Pesticides on Non-Target Species Office of Science and Technology
  13. Pesticide Chemistry v.4 Pyysalo, H.;J. Miyamoto(ed.);P. C. Kearney(ed.)
  14. J. Assoc. of Anal. Chem. v.54 Stoherr, R. W.;Ott, P.;R. R. Watts
  15. Gas Chromatography Willet, J.
  16. Scientific American v.216 Toxic Substances and Ecological Cycles Woodwell, G. M.