Journal of the Korean Magnetic Resonance Society (한국자기공명학회논문지)

Korean Magnetic Resonance Society (한국자기공명학회)
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Deuterium NMR Studies of $({\mu}_3-C^2H)[Co(CO)_3]_3$

  • Woo, Ae-Ja (Department of Science Education, Ewha Womans University) ;
  • Maria I. Altbach (Department of Chemistry, Louisiana State University) ;
  • Leslie G. Butler (Department of Chemistry, Louisiana State University)
  • Published : 1997.12.01
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Abstract

Deuterium quadrupole coupling constant (e2qzzQ/h) of ($\mu$3-C2H)[Co(CO)3]3 was determined by using solid-state deuterium MAS NMR spectroscopy. The small quadrupole coupling constant of bridging methyne unit relative to sp-acethylene in propyne is discussed in terms of the C-H bond length and the negative charge on the carbon.

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